Copolymerization of tetradecene-1 and octene-1 with silyl-protected 10-undecen-1-ol using a C s-symmetry hafnium metallocene catalyst. A route to functionalized poly(α-olefins)

Vasilios Kotzabasakis; Nikolaus Petzetakis; Marinos Pitsikalis; Nikos Hadjichristidis; David J. Lohse

doi:10.1002/pola.23202

Copolymerization of tetradecene-1 and octene-1 with silyl-protected 10-undecen-1-ol using a C _s-symmetry hafnium metallocene catalyst. A route to functionalized poly(α-olefins)

Vasilios Kotzabasakis, Nikolaus Petzetakis, Marinos Pitsikalis, Nikos Hadjichristidis^*, David J. Lohse

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

Statistical copolymers of tetradecene-1 and octene-1 with 1-tert-butyl-dimethylsilyloxy-10-undecene were synthesized by metallocene catalyzed copolymerization. The C _s-symmetry hafnium metallocene [(p-Et ₃Si)Ph] ₂C(2,7-di-iert-BuFlu) (Cp)Hf(CH ₃) ₂ and tetrakis(pentafluorophenyl) borate dimethylanilinium salt ([B(C ₆F ₅) ₄] ^-[Me ₂NHPh] ⁺) were employed as the catalytic system, in the presence of trioctylaluminum (TOA) as a scavenger. The monomer reactivity ratios were calculated using the Finemann-Ross, inverted Finemann-Ross, and Kelen-Tüdos graphical methods. The structural parameters of the different copolymers were obtained from the calculation of the dyad monomer sequence fractions and the mean sequence lengths derived via the reactivity ratios.

Original language	English (US)
Pages (from-to)	876-886
Number of pages	11
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	47
Issue number	3
DOIs	https://doi.org/10.1002/pola.23202
State	Published - Feb 1 2009
Externally published	Yes

Keywords

Copolymerization
Gel permeation chromatography (GPC)
Metallocene catalysts
NMR
Polyolefins
Protected olefins

ASJC Scopus subject areas

Polymers and Plastics
Organic Chemistry
Materials Chemistry

Access to Document

10.1002/pola.23202

Cite this

Kotzabasakis, V., Petzetakis, N., Pitsikalis, M., Hadjichristidis, N., & Lohse, D. J. (2009). Copolymerization of tetradecene-1 and octene-1 with silyl-protected 10-undecen-1-ol using a C _s-symmetry hafnium metallocene catalyst. A route to functionalized poly(α-olefins). Journal of Polymer Science, Part A: Polymer Chemistry, 47(3), 876-886. https://doi.org/10.1002/pola.23202

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title = "Copolymerization of tetradecene-1 and octene-1 with silyl-protected 10-undecen-1-ol using a C s-symmetry hafnium metallocene catalyst. A route to functionalized poly(α-olefins)",

abstract = "Statistical copolymers of tetradecene-1 and octene-1 with 1-tert-butyl-dimethylsilyloxy-10-undecene were synthesized by metallocene catalyzed copolymerization. The C s-symmetry hafnium metallocene [(p-Et 3Si)Ph] 2C(2,7-di-iert-BuFlu) (Cp)Hf(CH 3) 2 and tetrakis(pentafluorophenyl) borate dimethylanilinium salt ([B(C 6F 5) 4] -[Me 2NHPh] +) were employed as the catalytic system, in the presence of trioctylaluminum (TOA) as a scavenger. The monomer reactivity ratios were calculated using the Finemann-Ross, inverted Finemann-Ross, and Kelen-T{\"u}dos graphical methods. The structural parameters of the different copolymers were obtained from the calculation of the dyad monomer sequence fractions and the mean sequence lengths derived via the reactivity ratios.",

keywords = "Copolymerization, Gel permeation chromatography (GPC), Metallocene catalysts, NMR, Polyolefins, Protected olefins",

author = "Vasilios Kotzabasakis and Nikolaus Petzetakis and Marinos Pitsikalis and Nikos Hadjichristidis and Lohse, {David J.}",

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doi = "10.1002/pola.23202",

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Kotzabasakis, V, Petzetakis, N, Pitsikalis, M, Hadjichristidis, N & Lohse, DJ 2009, 'Copolymerization of tetradecene-1 and octene-1 with silyl-protected 10-undecen-1-ol using a C _s-symmetry hafnium metallocene catalyst. A route to functionalized poly(α-olefins)', Journal of Polymer Science, Part A: Polymer Chemistry, vol. 47, no. 3, pp. 876-886. https://doi.org/10.1002/pola.23202

Copolymerization of tetradecene-1 and octene-1 with silyl-protected 10-undecen-1-ol using a C _s-symmetry hafnium metallocene catalyst. A route to functionalized poly(α-olefins). / Kotzabasakis, Vasilios; Petzetakis, Nikolaus; Pitsikalis, Marinos et al.
In: Journal of Polymer Science, Part A: Polymer Chemistry, Vol. 47, No. 3, 01.02.2009, p. 876-886.

Research output: Contribution to journal › Article › peer-review

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T1 - Copolymerization of tetradecene-1 and octene-1 with silyl-protected 10-undecen-1-ol using a C s-symmetry hafnium metallocene catalyst. A route to functionalized poly(α-olefins)

AU - Kotzabasakis, Vasilios

AU - Petzetakis, Nikolaus

AU - Pitsikalis, Marinos

AU - Hadjichristidis, Nikos

AU - Lohse, David J.

PY - 2009/2/1

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N2 - Statistical copolymers of tetradecene-1 and octene-1 with 1-tert-butyl-dimethylsilyloxy-10-undecene were synthesized by metallocene catalyzed copolymerization. The C s-symmetry hafnium metallocene [(p-Et 3Si)Ph] 2C(2,7-di-iert-BuFlu) (Cp)Hf(CH 3) 2 and tetrakis(pentafluorophenyl) borate dimethylanilinium salt ([B(C 6F 5) 4] -[Me 2NHPh] +) were employed as the catalytic system, in the presence of trioctylaluminum (TOA) as a scavenger. The monomer reactivity ratios were calculated using the Finemann-Ross, inverted Finemann-Ross, and Kelen-Tüdos graphical methods. The structural parameters of the different copolymers were obtained from the calculation of the dyad monomer sequence fractions and the mean sequence lengths derived via the reactivity ratios.

AB - Statistical copolymers of tetradecene-1 and octene-1 with 1-tert-butyl-dimethylsilyloxy-10-undecene were synthesized by metallocene catalyzed copolymerization. The C s-symmetry hafnium metallocene [(p-Et 3Si)Ph] 2C(2,7-di-iert-BuFlu) (Cp)Hf(CH 3) 2 and tetrakis(pentafluorophenyl) borate dimethylanilinium salt ([B(C 6F 5) 4] -[Me 2NHPh] +) were employed as the catalytic system, in the presence of trioctylaluminum (TOA) as a scavenger. The monomer reactivity ratios were calculated using the Finemann-Ross, inverted Finemann-Ross, and Kelen-Tüdos graphical methods. The structural parameters of the different copolymers were obtained from the calculation of the dyad monomer sequence fractions and the mean sequence lengths derived via the reactivity ratios.

KW - Copolymerization

KW - Gel permeation chromatography (GPC)

KW - Metallocene catalysts

KW - NMR

KW - Polyolefins

KW - Protected olefins

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