TY - JOUR
T1 - Cross-Coupling of Sodium Sulfinates with Aryl, Heteroaryl and Vinyl Halides by Nickel/photoredox dual catalysis
AU - Yue, Huifeng
AU - Zhu, Chen
AU - Rueping, Magnus
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: H.Y. acknowledges the China Scholarship Council. The research leading to these results has received funding from the European Research Council under the European Union's Seventh Framework Programme (FP/2007-2013) / ERC Grant Agreement no. 617044 (SunCatChem).
PY - 2018/1/5
Y1 - 2018/1/5
N2 - An efficient photoredox/nickel dual catalyzed sulfonylation reaction of aryl, heteroaryl, and vinyl halides has been achieved for the first time. This newly developed sulfonylation protocol provides a versatile method for the synthesis of diverse aromatic sulfones at room temperature and shows excellent functional group tolerance. The electrophilic coupling partners are not limited to aryl, heteroaryl and vinyl bromides but also less reactive aryl chlorides are suitable substrates for this transformation.
AB - An efficient photoredox/nickel dual catalyzed sulfonylation reaction of aryl, heteroaryl, and vinyl halides has been achieved for the first time. This newly developed sulfonylation protocol provides a versatile method for the synthesis of diverse aromatic sulfones at room temperature and shows excellent functional group tolerance. The electrophilic coupling partners are not limited to aryl, heteroaryl and vinyl bromides but also less reactive aryl chlorides are suitable substrates for this transformation.
UR - http://hdl.handle.net/10754/626369
UR - http://onlinelibrary.wiley.com/doi/10.1002/anie.201711104/abstract
UR - http://www.scopus.com/inward/record.url?scp=85040825571&partnerID=8YFLogxK
U2 - 10.1002/anie.201711104
DO - 10.1002/anie.201711104
M3 - Article
C2 - 29211330
SN - 1433-7851
VL - 57
SP - 1371
EP - 1375
JO - Angewandte Chemie International Edition
JF - Angewandte Chemie International Edition
IS - 5
ER -