Crosslinked Remote-Doped Hole-Extracting Contacts Enhance Stability under Accelerated Lifetime Testing in Perovskite Solar Cells

Jixian Xu; Oleksandr Voznyy; Riccardo Comin; Xiwen Gong; Grant Walters; Min Liu; Pongsakorn Kanjanaboos; Xinzheng Lan; Edward H. Sargent

doi:10.1002/adma.201505630

Crosslinked Remote-Doped Hole-Extracting Contacts Enhance Stability under Accelerated Lifetime Testing in Perovskite Solar Cells

Jixian Xu, Oleksandr Voznyy, Riccardo Comin, Xiwen Gong, Grant Walters, Min Liu, Pongsakorn Kanjanaboos, Xinzheng Lan, Edward H. Sargent

Research output: Contribution to journal › Article › peer-review

109 Scopus citations

Abstract

A crosslinked hole-extracting electrical contact is reported, which simultaneously improves the stability and lowers the hysteresis of perovskite solar cells. Polymerizable monomers and crosslinking processes are developed to obviate in situ degradation of the under lying perovskite. The crosslinked material is band-aligned with perovskite. The required free carrier density is induced by a high-work-function metal oxide layer atop the device, following a remote-doping strategy.

Original language	English (US)
Pages (from-to)	2807-2815
Number of pages	9
Journal	ADVANCED MATERIALS
Volume	28
Issue number	14
DOIs	https://doi.org/10.1002/adma.201505630
State	Published - Jan 29 2016
Externally published	Yes

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title = "Crosslinked Remote-Doped Hole-Extracting Contacts Enhance Stability under Accelerated Lifetime Testing in Perovskite Solar Cells",

abstract = "A crosslinked hole-extracting electrical contact is reported, which simultaneously improves the stability and lowers the hysteresis of perovskite solar cells. Polymerizable monomers and crosslinking processes are developed to obviate in situ degradation of the under lying perovskite. The crosslinked material is band-aligned with perovskite. The required free carrier density is induced by a high-work-function metal oxide layer atop the device, following a remote-doping strategy.",

author = "Jixian Xu and Oleksandr Voznyy and Riccardo Comin and Xiwen Gong and Grant Walters and Min Liu and Pongsakorn Kanjanaboos and Xinzheng Lan and Sargent, {Edward H.}",

note = "KAUST Repository Item: Exported on 2022-05-31 Acknowledged KAUST grant number(s): KUS-11-009-21 Acknowledgements: This publication is based in part on work supported by Award KUS-11-009-21, made by King Abdullah University of Science and Technology (KAUST), by the Ontario Research Fund - Research Excellence Program, and by the Natural Sciences and Engineering Research Council (NSERC) of Canada. The authors thank R. Wolowiec and D. Kopilovic for their technical support. The authors thank Dr. Yongbiao Zhao and Yiying Li's help on UPS measurements. This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

year = "2016",

month = jan,

day = "29",

doi = "10.1002/adma.201505630",

language = "English (US)",

volume = "28",

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journal = "ADVANCED MATERIALS",

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T1 - Crosslinked Remote-Doped Hole-Extracting Contacts Enhance Stability under Accelerated Lifetime Testing in Perovskite Solar Cells

AU - Xu, Jixian

AU - Voznyy, Oleksandr

AU - Comin, Riccardo

AU - Gong, Xiwen

AU - Walters, Grant

AU - Liu, Min

AU - Kanjanaboos, Pongsakorn

AU - Lan, Xinzheng

AU - Sargent, Edward H.

N1 - KAUST Repository Item: Exported on 2022-05-31 Acknowledged KAUST grant number(s): KUS-11-009-21 Acknowledgements: This publication is based in part on work supported by Award KUS-11-009-21, made by King Abdullah University of Science and Technology (KAUST), by the Ontario Research Fund - Research Excellence Program, and by the Natural Sciences and Engineering Research Council (NSERC) of Canada. The authors thank R. Wolowiec and D. Kopilovic for their technical support. The authors thank Dr. Yongbiao Zhao and Yiying Li's help on UPS measurements. This publication acknowledges KAUST support, but has no KAUST affiliated authors.

PY - 2016/1/29

Y1 - 2016/1/29

N2 - A crosslinked hole-extracting electrical contact is reported, which simultaneously improves the stability and lowers the hysteresis of perovskite solar cells. Polymerizable monomers and crosslinking processes are developed to obviate in situ degradation of the under lying perovskite. The crosslinked material is band-aligned with perovskite. The required free carrier density is induced by a high-work-function metal oxide layer atop the device, following a remote-doping strategy.

AB - A crosslinked hole-extracting electrical contact is reported, which simultaneously improves the stability and lowers the hysteresis of perovskite solar cells. Polymerizable monomers and crosslinking processes are developed to obviate in situ degradation of the under lying perovskite. The crosslinked material is band-aligned with perovskite. The required free carrier density is induced by a high-work-function metal oxide layer atop the device, following a remote-doping strategy.

UR - http://hdl.handle.net/10754/678338

UR - https://onlinelibrary.wiley.com/doi/10.1002/adma.201505630

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JO - ADVANCED MATERIALS

JF - ADVANCED MATERIALS

IS - 14

ER -

Crosslinked Remote-Doped Hole-Extracting Contacts Enhance Stability under Accelerated Lifetime Testing in Perovskite Solar Cells

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