Crystal chemistry of three new monodimensional fluorometalates templated with ethylenediamine

J. Lhoste; R. Gervier; V. Maisonneuve; M. Leblanc; K. Adil

doi:10.1016/j.solidstatesciences.2009.06.020

Crystal chemistry of three new monodimensional fluorometalates templated with ethylenediamine

J. Lhoste, R. Gervier, V. Maisonneuve, M. Leblanc, K. Adil^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Three new monodimensional hybrid metal (Ti, In, Al) fluorides are synthesized with ethylenediamine (en) as a templating agent in solvothermal conditions assisted by microwave heating. All structures involve inorganic chains built up from TiO₂F₄ octahedra connected by two opposite O^2- vertices in [H₂en]·(TiOF₄) (I), from InF₆(H₂O) pentagonal bipyramids linked by F-F edges in [H₂en]·(InF₄(H₂O))₂·H₂O (II) and from (Al₇F₃₀)^9- polyanions sharing two opposite AlF₆ octahedra in [H₂en]₃·(Al₆F₂₄) (III). I is tetragonal, P4/ncc, a = 12.761(3) Å, c = 8.041(3) Å; II is orthorhombic, F2dd, a = 6.904(5) Å, b = 16.559(5) Å, c = 19.777(4) Å and III is monoclinic, P2₁/n, a = 9.387(2) Å, b = 6.710(2) Å, c = 21.513(6) Å, β = 97.18(3)°.

Original language	English (US)
Pages (from-to)	1582-1586
Number of pages	5
Journal	Solid State Sciences
Volume	11
Issue number	9
DOIs	https://doi.org/10.1016/j.solidstatesciences.2009.06.020
State	Published - Sep 2009
Externally published	Yes

Keywords

Crystal structure
Ethylenediamine
Fluoride
Microwave heating
Solvothermal synthesis

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1016/j.solidstatesciences.2009.06.020

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@article{b252084399214fe79746fbc05a4e141a,

title = "Crystal chemistry of three new monodimensional fluorometalates templated with ethylenediamine",

abstract = "Three new monodimensional hybrid metal (Ti, In, Al) fluorides are synthesized with ethylenediamine (en) as a templating agent in solvothermal conditions assisted by microwave heating. All structures involve inorganic chains built up from TiO2F4 octahedra connected by two opposite O2- vertices in [H2en]·(TiOF4) (I), from InF6(H2O) pentagonal bipyramids linked by F-F edges in [H2en]·(InF4(H2O))2·H2O (II) and from (Al7F30)9- polyanions sharing two opposite AlF6 octahedra in [H2en]3·(Al6F24) (III). I is tetragonal, P4/ncc, a = 12.761(3) {\AA}, c = 8.041(3) {\AA}; II is orthorhombic, F2dd, a = 6.904(5) {\AA}, b = 16.559(5) {\AA}, c = 19.777(4) {\AA} and III is monoclinic, P21/n, a = 9.387(2) {\AA}, b = 6.710(2) {\AA}, c = 21.513(6) {\AA}, β = 97.18(3)°.",

keywords = "Crystal structure, Ethylenediamine, Fluoride, Microwave heating, Solvothermal synthesis",

author = "J. Lhoste and R. Gervier and V. Maisonneuve and M. Leblanc and K. Adil",

year = "2009",

month = sep,

doi = "10.1016/j.solidstatesciences.2009.06.020",

language = "English (US)",

volume = "11",

pages = "1582--1586",

journal = "Solid State Sciences",

issn = "1293-2558",

publisher = "Elsevier Masson SAS",

number = "9",

}

TY - JOUR

T1 - Crystal chemistry of three new monodimensional fluorometalates templated with ethylenediamine

AU - Lhoste, J.

AU - Gervier, R.

AU - Maisonneuve, V.

AU - Leblanc, M.

AU - Adil, K.

PY - 2009/9

Y1 - 2009/9

N2 - Three new monodimensional hybrid metal (Ti, In, Al) fluorides are synthesized with ethylenediamine (en) as a templating agent in solvothermal conditions assisted by microwave heating. All structures involve inorganic chains built up from TiO2F4 octahedra connected by two opposite O2- vertices in [H2en]·(TiOF4) (I), from InF6(H2O) pentagonal bipyramids linked by F-F edges in [H2en]·(InF4(H2O))2·H2O (II) and from (Al7F30)9- polyanions sharing two opposite AlF6 octahedra in [H2en]3·(Al6F24) (III). I is tetragonal, P4/ncc, a = 12.761(3) Å, c = 8.041(3) Å; II is orthorhombic, F2dd, a = 6.904(5) Å, b = 16.559(5) Å, c = 19.777(4) Å and III is monoclinic, P21/n, a = 9.387(2) Å, b = 6.710(2) Å, c = 21.513(6) Å, β = 97.18(3)°.

AB - Three new monodimensional hybrid metal (Ti, In, Al) fluorides are synthesized with ethylenediamine (en) as a templating agent in solvothermal conditions assisted by microwave heating. All structures involve inorganic chains built up from TiO2F4 octahedra connected by two opposite O2- vertices in [H2en]·(TiOF4) (I), from InF6(H2O) pentagonal bipyramids linked by F-F edges in [H2en]·(InF4(H2O))2·H2O (II) and from (Al7F30)9- polyanions sharing two opposite AlF6 octahedra in [H2en]3·(Al6F24) (III). I is tetragonal, P4/ncc, a = 12.761(3) Å, c = 8.041(3) Å; II is orthorhombic, F2dd, a = 6.904(5) Å, b = 16.559(5) Å, c = 19.777(4) Å and III is monoclinic, P21/n, a = 9.387(2) Å, b = 6.710(2) Å, c = 21.513(6) Å, β = 97.18(3)°.

KW - Crystal structure

KW - Ethylenediamine

KW - Fluoride

KW - Microwave heating

KW - Solvothermal synthesis

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U2 - 10.1016/j.solidstatesciences.2009.06.020

DO - 10.1016/j.solidstatesciences.2009.06.020

M3 - Article

AN - SCOPUS:68949214293

SN - 1293-2558

VL - 11

SP - 1582

EP - 1586

JO - Solid State Sciences

JF - Solid State Sciences

IS - 9

ER -

Crystal chemistry of three new monodimensional fluorometalates templated with ethylenediamine

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