Abstract
In the title compound, [FeIr(C5H5)(C20H14N3)Cl3]·2CH3CN, the central IrIII atom is sixfold coordinated by three chloride ligands and three terpyridine N atoms in a slightly distorted octahedral fashion. The terpyridine ligand is functionalized at the 4'-position with a ferrocenyl group, the latter being in an eclipsed conformation. In the crystal, molecules are stacked in rows parallel to [001], with the acetonitrile solvent molecules situated between the rows. An extensive network of intra- and intermolecular C-H...Cl interactions is present, stabilizing the three-dimensional structure.
| Original language | English (US) |
|---|---|
| Pages (from-to) | m69-m70 |
| Number of pages | 1 |
| Journal | Acta Crystallographica Section E Crystallographic Communications |
| Volume | 71 |
| Issue number | 3 |
| DOIs | |
| State | Published - Feb 25 2015 |
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Dive into the research topics of 'Crystal structure of trichlorido(4'-ferrocenyl-2,2':6',2''-terpyridine-[kappa]3N,N',N'')iridium(III) acetonitrile disolvate'. Together they form a unique fingerprint.Datasets
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CCDC 1050374: Experimental Crystal Structure Determination : trichloro-(4'-ferrocenyl-2,2':6',2''-terpyridine)-iridium(iii) acetonitrile solvate
Davaasuren, B. (Creator), Padhy, H. (Creator) & Rothenberger, A. (Creator), Cambridge Crystallographic Data Centre, Feb 25 2015
DOI: 10.5517/cc14801g, http://hdl.handle.net/10754/624413
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