CsPb2Br5 Single Crystals: Synthesis and Characterization

Ibrahim Dursun; Michele de Bastiani; Bekir Turedi; Badriah Jaber Alamer; Aleksander Shkurenko; Jun Yin; Issam Gereige; Ahmed Alsaggaf; Omar F. Mohammed; Mohamed Eddaoudi; Osman Bakr

doi:10.1002/cssc.201701131

CsPb2Br5 Single Crystals: Synthesis and Characterization

Ibrahim Dursun, Michele de Bastiani, Bekir Turedi, Badriah Jaber Alamer, Aleksander Shkurenko, Jun Yin, Issam Gereige, Ahmed Alsaggaf, Omar F. Mohammed, Mohamed Eddaoudi, Osman Bakr

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139 Scopus citations

Abstract

CsPb2Br5 is a ternary halogen-plumbate material with close characteristics to well-reported halide perovskites. Due to its unconventional two-dimensional structure, CsPb2Br5 is being looked at broadly for potential applications in optoelectronics. CsPb2Br5 investigations are currently limited to nanostructures and powder forms of the material, which present unclear and conflicting optical properties. In this study, we present the synthesis and characterization of CsPb2Br5 bulk single crystals, which enabled us to finally clarify the material's optical features. Our CsPb2Br5 crystal has a two-dimensional structure with Pb2Br5- layers spaced by Cs+ cations, and exhibits a ~3.1 eV indirect bandgap with no emission in the visible spectrum.

Original language	English (US)
Pages (from-to)	3746-3749
Number of pages	4
Journal	ChemSusChem
Volume	10
Issue number	19
DOIs	https://doi.org/10.1002/cssc.201701131
State	Published - Aug 30 2017

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10.1002/cssc.201701131

https://repository.kaust.edu.sa/bitstream/10754/625293/1/Dursun_et_al-2017-ChemSusChem.pdf

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title = "CsPb2Br5 Single Crystals: Synthesis and Characterization",

abstract = "CsPb2Br5 is a ternary halogen-plumbate material with close characteristics to well-reported halide perovskites. Due to its unconventional two-dimensional structure, CsPb2Br5 is being looked at broadly for potential applications in optoelectronics. CsPb2Br5 investigations are currently limited to nanostructures and powder forms of the material, which present unclear and conflicting optical properties. In this study, we present the synthesis and characterization of CsPb2Br5 bulk single crystals, which enabled us to finally clarify the material's optical features. Our CsPb2Br5 crystal has a two-dimensional structure with Pb2Br5- layers spaced by Cs+ cations, and exhibits a ~3.1 eV indirect bandgap with no emission in the visible spectrum.",

author = "Ibrahim Dursun and {de Bastiani}, Michele and Bekir Turedi and Alamer, {Badriah Jaber} and Aleksander Shkurenko and Jun Yin and Issam Gereige and Ahmed Alsaggaf and Mohammed, {Omar F.} and Mohamed Eddaoudi and Osman Bakr",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The authors acknowledge the financial support of King Abdullah University of Science and Technology (KAUST) and Saudi Aramco.",

year = "2017",

month = aug,

day = "30",

doi = "10.1002/cssc.201701131",

language = "English (US)",

volume = "10",

pages = "3746--3749",

journal = "ChemSusChem",

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TY - JOUR

T1 - CsPb2Br5 Single Crystals: Synthesis and Characterization

AU - Dursun, Ibrahim

AU - de Bastiani, Michele

AU - Turedi, Bekir

AU - Alamer, Badriah Jaber

AU - Shkurenko, Aleksander

AU - Yin, Jun

AU - Gereige, Issam

AU - Alsaggaf, Ahmed

AU - Mohammed, Omar F.

AU - Eddaoudi, Mohamed

AU - Bakr, Osman

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The authors acknowledge the financial support of King Abdullah University of Science and Technology (KAUST) and Saudi Aramco.

PY - 2017/8/30

Y1 - 2017/8/30

N2 - CsPb2Br5 is a ternary halogen-plumbate material with close characteristics to well-reported halide perovskites. Due to its unconventional two-dimensional structure, CsPb2Br5 is being looked at broadly for potential applications in optoelectronics. CsPb2Br5 investigations are currently limited to nanostructures and powder forms of the material, which present unclear and conflicting optical properties. In this study, we present the synthesis and characterization of CsPb2Br5 bulk single crystals, which enabled us to finally clarify the material's optical features. Our CsPb2Br5 crystal has a two-dimensional structure with Pb2Br5- layers spaced by Cs+ cations, and exhibits a ~3.1 eV indirect bandgap with no emission in the visible spectrum.

AB - CsPb2Br5 is a ternary halogen-plumbate material with close characteristics to well-reported halide perovskites. Due to its unconventional two-dimensional structure, CsPb2Br5 is being looked at broadly for potential applications in optoelectronics. CsPb2Br5 investigations are currently limited to nanostructures and powder forms of the material, which present unclear and conflicting optical properties. In this study, we present the synthesis and characterization of CsPb2Br5 bulk single crystals, which enabled us to finally clarify the material's optical features. Our CsPb2Br5 crystal has a two-dimensional structure with Pb2Br5- layers spaced by Cs+ cations, and exhibits a ~3.1 eV indirect bandgap with no emission in the visible spectrum.

UR - http://hdl.handle.net/10754/625293

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DO - 10.1002/cssc.201701131

M3 - Article

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SN - 1864-5631

VL - 10

SP - 3746

EP - 3749

JO - ChemSusChem

JF - ChemSusChem

IS - 19

ER -

CsPb2Br5 Single Crystals: Synthesis and Characterization

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