Cu2[o-Br C6H3(CO2)2]2(H 2O)2· (DMF)8(H2O)2: A framework deliberately designed to have the Nbo structure type

Mohamed Eddaoudi; Jaheon Kim; Michael O'Keeffe; Omar M. Yaghi

doi:10.1021/ja017154e

Cu₂[o-Br C₆H₃(CO₂)₂]₂(H ₂O)₂· (DMF)₈(H₂O)₂: A framework deliberately designed to have the Nbo structure type

Mohamed Eddaoudi, Jaheon Kim, Michael O'Keeffe, Omar M. Yaghi^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

391 Scopus citations

Abstract

The synthesis of an NbO-type metal-organic framework was achieved by design: o-Br-BDC (BDC = benzenedicarboxylate) was used to direct the formation of Cu₂(CO₂)₄ paddle wheel units at 90° to each other and thus yield the target network. The compound was formulated as Cu₂[o-Br-BDC]₂(H₂O)₂·(DMF)₈(H₂O)₂ (MOF-101) and characterized by single-crystal X-ray diffraction [cubic, space group lm3m (No. 229) with a = 21.607(3) Å, V = 10088(2) Å³, Z = 6], which fully confirmed the presence of the expected structure. Despite having very large apertures and voids, MOF-101 has a noninterpenetrated structure, an intriguing observation that is discussed in the context of dual structures.

Original language	English (US)
Pages (from-to)	376-377
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	124
Issue number	3
DOIs	https://doi.org/10.1021/ja017154e
State	Published - Jan 23 2002
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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@article{69279733fb15401cb3269d474abf4f3a,

title = "Cu2[o-Br C6H3(CO2)2]2(H 2O)2· (DMF)8(H2O)2: A framework deliberately designed to have the Nbo structure type",

abstract = "The synthesis of an NbO-type metal-organic framework was achieved by design: o-Br-BDC (BDC = benzenedicarboxylate) was used to direct the formation of Cu2(CO2)4 paddle wheel units at 90° to each other and thus yield the target network. The compound was formulated as Cu2[o-Br-BDC]2(H2O)2·(DMF)8(H2O)2 (MOF-101) and characterized by single-crystal X-ray diffraction [cubic, space group lm3m (No. 229) with a = 21.607(3) {\AA}, V = 10088(2) {\AA}3, Z = 6], which fully confirmed the presence of the expected structure. Despite having very large apertures and voids, MOF-101 has a noninterpenetrated structure, an intriguing observation that is discussed in the context of dual structures.",

author = "Mohamed Eddaoudi and Jaheon Kim and Michael O'Keeffe and Yaghi, {Omar M.}",

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T1 - Cu2[o-Br C6H3(CO2)2]2(H 2O)2· (DMF)8(H2O)2

T2 - A framework deliberately designed to have the Nbo structure type

AU - Eddaoudi, Mohamed

AU - Kim, Jaheon

AU - O'Keeffe, Michael

AU - Yaghi, Omar M.

PY - 2002/1/23

Y1 - 2002/1/23

N2 - The synthesis of an NbO-type metal-organic framework was achieved by design: o-Br-BDC (BDC = benzenedicarboxylate) was used to direct the formation of Cu2(CO2)4 paddle wheel units at 90° to each other and thus yield the target network. The compound was formulated as Cu2[o-Br-BDC]2(H2O)2·(DMF)8(H2O)2 (MOF-101) and characterized by single-crystal X-ray diffraction [cubic, space group lm3m (No. 229) with a = 21.607(3) Å, V = 10088(2) Å3, Z = 6], which fully confirmed the presence of the expected structure. Despite having very large apertures and voids, MOF-101 has a noninterpenetrated structure, an intriguing observation that is discussed in the context of dual structures.

AB - The synthesis of an NbO-type metal-organic framework was achieved by design: o-Br-BDC (BDC = benzenedicarboxylate) was used to direct the formation of Cu2(CO2)4 paddle wheel units at 90° to each other and thus yield the target network. The compound was formulated as Cu2[o-Br-BDC]2(H2O)2·(DMF)8(H2O)2 (MOF-101) and characterized by single-crystal X-ray diffraction [cubic, space group lm3m (No. 229) with a = 21.607(3) Å, V = 10088(2) Å3, Z = 6], which fully confirmed the presence of the expected structure. Despite having very large apertures and voids, MOF-101 has a noninterpenetrated structure, an intriguing observation that is discussed in the context of dual structures.

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Cu₂[o-Br C₆H₃(CO₂)₂]₂(H ₂O)₂· (DMF)₈(H₂O)₂: A framework deliberately designed to have the Nbo structure type

Abstract

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