Cyanated diazatetracene diimides with ultrahigh electron affinity for n-channel field effect transistors

Qun Ye; Jingjing Chang; Kuo-Wei Huang; Xueliang Shi; Jishan Wu; Chunyan Chi

doi:10.1021/ol400082c

Cyanated diazatetracene diimides with ultrahigh electron affinity for n-channel field effect transistors

Qun Ye, Jingjing Chang, Kuo-Wei Huang, Xueliang Shi, Jishan Wu, Chunyan Chi

Research output: Contribution to journal › Article › peer-review

71 Scopus citations

Abstract

Several diazatetracene diimides with high electron affinity (up to 4.66 eV!) were prepared and well characterized. The LUMO energy level of these electron-deficient molecules was found to be closely related to their material stability. Compound 7 with ultrahigh electron affinity suffered from reduction and hydrolysis in the presence of silica gel or water. The stable compounds 3 and 6 showed n-channel FET behavior with an average electron mobility of 0.002 and 0.005 cm2 V-1 s-1, respectively, using a solution processing method. © 2013 American Chemical Society.

Original language	English (US)
Pages (from-to)	1194-1197
Number of pages	4
Journal	Organic Letters
Volume	15
Issue number	6
DOIs	https://doi.org/10.1021/ol400082c
State	Published - Mar 5 2013

ASJC Scopus subject areas

Biochemistry
Organic Chemistry
Physical and Theoretical Chemistry

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10.1021/ol400082c

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@article{f1f9b242d9df4dc484565105db047348,

title = "Cyanated diazatetracene diimides with ultrahigh electron affinity for n-channel field effect transistors",

abstract = "Several diazatetracene diimides with high electron affinity (up to 4.66 eV!) were prepared and well characterized. The LUMO energy level of these electron-deficient molecules was found to be closely related to their material stability. Compound 7 with ultrahigh electron affinity suffered from reduction and hydrolysis in the presence of silica gel or water. The stable compounds 3 and 6 showed n-channel FET behavior with an average electron mobility of 0.002 and 0.005 cm2 V-1 s-1, respectively, using a solution processing method. {\textcopyright} 2013 American Chemical Society.",

author = "Qun Ye and Jingjing Chang and Kuo-Wei Huang and Xueliang Shi and Jishan Wu and Chunyan Chi",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was financially supported by the National University of Singapore Start-Up Grant (R-143-000-486-133), MOE AcRF FRC grant (R-143-000-510-112), IMRE Core funding (IMRE/10-1P0509), and KAUST (K.-W.H.).",

year = "2013",

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doi = "10.1021/ol400082c",

language = "English (US)",

volume = "15",

pages = "1194--1197",

journal = "Organic Letters",

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TY - JOUR

T1 - Cyanated diazatetracene diimides with ultrahigh electron affinity for n-channel field effect transistors

AU - Ye, Qun

AU - Chang, Jingjing

AU - Huang, Kuo-Wei

AU - Shi, Xueliang

AU - Wu, Jishan

AU - Chi, Chunyan

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was financially supported by the National University of Singapore Start-Up Grant (R-143-000-486-133), MOE AcRF FRC grant (R-143-000-510-112), IMRE Core funding (IMRE/10-1P0509), and KAUST (K.-W.H.).

PY - 2013/3/5

Y1 - 2013/3/5

N2 - Several diazatetracene diimides with high electron affinity (up to 4.66 eV!) were prepared and well characterized. The LUMO energy level of these electron-deficient molecules was found to be closely related to their material stability. Compound 7 with ultrahigh electron affinity suffered from reduction and hydrolysis in the presence of silica gel or water. The stable compounds 3 and 6 showed n-channel FET behavior with an average electron mobility of 0.002 and 0.005 cm2 V-1 s-1, respectively, using a solution processing method. © 2013 American Chemical Society.

AB - Several diazatetracene diimides with high electron affinity (up to 4.66 eV!) were prepared and well characterized. The LUMO energy level of these electron-deficient molecules was found to be closely related to their material stability. Compound 7 with ultrahigh electron affinity suffered from reduction and hydrolysis in the presence of silica gel or water. The stable compounds 3 and 6 showed n-channel FET behavior with an average electron mobility of 0.002 and 0.005 cm2 V-1 s-1, respectively, using a solution processing method. © 2013 American Chemical Society.

UR - http://hdl.handle.net/10754/562684

UR - https://pubs.acs.org/doi/10.1021/ol400082c

UR - http://www.scopus.com/inward/record.url?scp=84875183407&partnerID=8YFLogxK

U2 - 10.1021/ol400082c

DO - 10.1021/ol400082c

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JO - Organic Letters

JF - Organic Letters

IS - 6

ER -

Cyanated diazatetracene diimides with ultrahigh electron affinity for n-channel field effect transistors

Abstract

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