Delivering the Full Potential of Oxygen Evolving Electrocatalyst by Conditioning Electrolytes at Near-Neutral pH

Takeshi Nishimoto, Tatsuya Shinagawa, Takahiro Naito, Kazuhiro Takanabe

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

This study reports on the impact of identity and compositions of buffer ions on oxygen evolution reaction (OER) performance at a wide range of pH levels using a model IrOx electrocatalyst. Rigorous microkinetic analysis employing kinetic isotope effects, Tafel analysis, and temperature dependence measurement was conducted to establish rate expression isolated from the diffusion contribution of buffer ions and solution resistance. It was found that the OER kinetics was facile with OH− oxidation compared to H2O, the results of which were highlighted by mitigating over 200 mV overpotential in the presence of buffer to reach 10 mA cm−2. This improvement was ascribed to the involvement of the kinetics of the local OH− supply by the buffering action. Further digesting the kinetic data at various buffer pKa and the solution bulk pH disclosed a trade-off between the exchange current density and the Tafel slope, indicating that the optimal electrolyte condition can be chosen at a different range of current density. This study provides a quantitative guideline for electrolyte engineering to maximize the intrinsic OER performance that electrocatalyst possesses especially at near-neutral pH.
Original languageEnglish (US)
Pages (from-to)1554-1564
Number of pages11
JournalChemSusChem
Volume14
Issue number6
DOIs
StatePublished - Jan 22 2021
Externally publishedYes

ASJC Scopus subject areas

  • General Energy
  • Environmental Chemistry
  • General Materials Science
  • General Chemical Engineering

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