Dendronized cyclocopolymers with a radial gradient of polarity and their use to catalyze a difficult esterification

Catherine O. Liang; Brett Helms; Craig J. Hawker; Jean M.J. Fréchet

doi:10.1039/b307425k

Dendronized cyclocopolymers with a radial gradient of polarity and their use to catalyze a difficult esterification

Catherine O. Liang, Brett Helms, Craig J. Hawker, Jean M.J. Fréchet^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

97 Scopus citations

Abstract

A cyclocopolymer containing pyrrolidinopyridine pendant groups was dendronized with polyester dendrons terminated with long alkyl chain ends and the microenvironment created by the dendrons was used to catalyze the difficult esterification of a tertiary alcohol with pivalic anhydride.

Original language	English (US)
Pages (from-to)	2524-2525
Number of pages	2
Journal	CHEMICAL COMMUNICATIONS
Volume	3
Issue number	20
DOIs	https://doi.org/10.1039/b307425k
State	Published - 2003
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Dendronized cyclocopolymers with a radial gradient of polarity and their use to catalyze a difficult esterification",

abstract = "A cyclocopolymer containing pyrrolidinopyridine pendant groups was dendronized with polyester dendrons terminated with long alkyl chain ends and the microenvironment created by the dendrons was used to catalyze the difficult esterification of a tertiary alcohol with pivalic anhydride.",

author = "Liang, {Catherine O.} and Brett Helms and Hawker, {Craig J.} and Fr{\'e}chet, {Jean M.J.}",

year = "2003",

doi = "10.1039/b307425k",

language = "English (US)",

volume = "3",

pages = "2524--2525",

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issn = "1359-7345",

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T1 - Dendronized cyclocopolymers with a radial gradient of polarity and their use to catalyze a difficult esterification

AU - Liang, Catherine O.

AU - Helms, Brett

AU - Hawker, Craig J.

AU - Fréchet, Jean M.J.

PY - 2003

Y1 - 2003

N2 - A cyclocopolymer containing pyrrolidinopyridine pendant groups was dendronized with polyester dendrons terminated with long alkyl chain ends and the microenvironment created by the dendrons was used to catalyze the difficult esterification of a tertiary alcohol with pivalic anhydride.

AB - A cyclocopolymer containing pyrrolidinopyridine pendant groups was dendronized with polyester dendrons terminated with long alkyl chain ends and the microenvironment created by the dendrons was used to catalyze the difficult esterification of a tertiary alcohol with pivalic anhydride.

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U2 - 10.1039/b307425k

DO - 10.1039/b307425k

M3 - Article

AN - SCOPUS:0142094062

SN - 1359-7345

VL - 3

SP - 2524

EP - 2525

JO - CHEMICAL COMMUNICATIONS

JF - CHEMICAL COMMUNICATIONS

IS - 20

ER -

Dendronized cyclocopolymers with a radial gradient of polarity and their use to catalyze a difficult esterification

Abstract

ASJC Scopus subject areas

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