Dependence of the regiospecificity on the type of stereospecificity in propene polymerization with catalytic systems based on zirconocenes

Gaetano Guerra; Luigi Cavallo; Paolo Corradini; Pasquale Longo; Luigi Resconi

Dependence of the regiospecificity on the type of stereospecificity in propene polymerization with catalytic systems based on zirconocenes

Gaetano Guerra^*, Luigi Cavallo, Paolo Corradini, Pasquale Longo, Luigi Resconi

^*Corresponding author for this work

Research output: Contribution to journal › Conference article › peer-review

1 Scopus citations

Abstract

Catalytic systems based on zirconocenes can produce polymers with an overall amount of regioirregular placements as high as 2-3%. The higher regiospecifities of titanocene based, with respect to zirconocene based, catalytic systems has been accounted for by the large contributions of the non-bonded interactions, in favor of the monomer coordination suitable for the primary insertion when shorter Mt-C distances are involved.

Original language	English (US)
Pages (from-to)	469
Number of pages	1
Journal	American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume	37
Issue number	2
State	Published - Aug 1996
Externally published	Yes
Event	Proceedings of the 1996 ACS Orlando Meeting - Orlando, FL, USA Duration: Aug 25 1996 → Aug 29 1996

ASJC Scopus subject areas

Polymers and Plastics

Cite this

@article{65f377e694784f8abf23d37147ff69f1,

title = "Dependence of the regiospecificity on the type of stereospecificity in propene polymerization with catalytic systems based on zirconocenes",

abstract = "Catalytic systems based on zirconocenes can produce polymers with an overall amount of regioirregular placements as high as 2-3%. The higher regiospecifities of titanocene based, with respect to zirconocene based, catalytic systems has been accounted for by the large contributions of the non-bonded interactions, in favor of the monomer coordination suitable for the primary insertion when shorter Mt-C distances are involved.",

author = "Gaetano Guerra and Luigi Cavallo and Paolo Corradini and Pasquale Longo and Luigi Resconi",

year = "1996",

month = aug,

language = "English (US)",

volume = "37",

pages = "469",

journal = "American Chemical Society, Polymer Preprints, Division of Polymer Chemistry",

issn = "0032-3934",

number = "2",

note = "Proceedings of the 1996 ACS Orlando Meeting ; Conference date: 25-08-1996 Through 29-08-1996",

}

Dependence of the regiospecificity on the type of stereospecificity in propene polymerization with catalytic systems based on zirconocenes. / Guerra, Gaetano; Cavallo, Luigi; Corradini, Paolo et al.
In: American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, Vol. 37, No. 2, 08.1996, p. 469.

Research output: Contribution to journal › Conference article › peer-review

TY - JOUR

T1 - Dependence of the regiospecificity on the type of stereospecificity in propene polymerization with catalytic systems based on zirconocenes

AU - Guerra, Gaetano

AU - Cavallo, Luigi

AU - Corradini, Paolo

AU - Longo, Pasquale

AU - Resconi, Luigi

PY - 1996/8

Y1 - 1996/8

N2 - Catalytic systems based on zirconocenes can produce polymers with an overall amount of regioirregular placements as high as 2-3%. The higher regiospecifities of titanocene based, with respect to zirconocene based, catalytic systems has been accounted for by the large contributions of the non-bonded interactions, in favor of the monomer coordination suitable for the primary insertion when shorter Mt-C distances are involved.

AB - Catalytic systems based on zirconocenes can produce polymers with an overall amount of regioirregular placements as high as 2-3%. The higher regiospecifities of titanocene based, with respect to zirconocene based, catalytic systems has been accounted for by the large contributions of the non-bonded interactions, in favor of the monomer coordination suitable for the primary insertion when shorter Mt-C distances are involved.

UR - http://www.scopus.com/inward/record.url?scp=0030204302&partnerID=8YFLogxK

M3 - Conference article

AN - SCOPUS:0030204302

SN - 0032-3934

VL - 37

SP - 469

JO - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

IS - 2

T2 - Proceedings of the 1996 ACS Orlando Meeting

Y2 - 25 August 1996 through 29 August 1996

ER -

Dependence of the regiospecificity on the type of stereospecificity in propene polymerization with catalytic systems based on zirconocenes

Abstract

ASJC Scopus subject areas

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