Design, synthesis, nonlinear spectroscopy and applications of two-photon absorbing molecules

D. Beljonne; Jean-Luc Bredas; B. H. Cumpston; J. Ehrlich; L. Erskine; A. A. Heikal; Z. Y. Hu; T. Kogej; I. Y.S. Lee; S. R. Marder; J. W. Perry; H. Rockel; S. Thayumanavan; X. L. Wu

Design, synthesis, nonlinear spectroscopy and applications of two-photon absorbing molecules

D. Beljonne^*, Jean-Luc Bredas, B. H. Cumpston, J. Ehrlich, L. Erskine, A. A. Heikal, Z. Y. Hu, T. Kogej, I. Y.S. Lee, S. R. Marder, J. W. Perry, H. Rockel, S. Thayumanavan, X. L. Wu

^*Corresponding author for this work

Physical Sciences and Engineering

Research output: Contribution to journal › Conference article › peer-review

Abstract

Large two-photon absorptivities in bis-donor diphenylpolyene derivatives were observed to determine their two-photon absorption spectra and to examine structure/two-photon spectra relationships. A simple bis donor-substituted stilbene had exceptionally large two-photon absorption cross section. Two-photon excitation of a variety of bis-donor diphenylpolyene derivatives in the presence of acrylate monomers led to the formation of polymers. With the two-photon absorbing molecule dissolved at 1% concentration in triacrylate monomer, an excitation of approximately 600 nm with an intensity of approximately 100 MW/cm ² yielded cross-linked polymer spots.

Original language	English (US)
Number of pages	1
Journal	American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume	38
Issue number	2
State	Published - Sep 1 1997
Event	Proceedings of the 1997 Las Vegas ACS Meeting - Las Vegas, NV, USA Duration: Sep 7 1997 → Sep 12 1997

ASJC Scopus subject areas

Polymers and Plastics

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Beljonne, D., Bredas, J-L., Cumpston, B. H., Ehrlich, J., Erskine, L., Heikal, A. A., Hu, Z. Y., Kogej, T., Lee, I. Y. S., Marder, S. R., Perry, J. W., Rockel, H., Thayumanavan, S., & Wu, X. L. (1997). Design, synthesis, nonlinear spectroscopy and applications of two-photon absorbing molecules. American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, 38(2).

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title = "Design, synthesis, nonlinear spectroscopy and applications of two-photon absorbing molecules",

abstract = " Large two-photon absorptivities in bis-donor diphenylpolyene derivatives were observed to determine their two-photon absorption spectra and to examine structure/two-photon spectra relationships. A simple bis donor-substituted stilbene had exceptionally large two-photon absorption cross section. Two-photon excitation of a variety of bis-donor diphenylpolyene derivatives in the presence of acrylate monomers led to the formation of polymers. With the two-photon absorbing molecule dissolved at 1% concentration in triacrylate monomer, an excitation of approximately 600 nm with an intensity of approximately 100 MW/cm 2 yielded cross-linked polymer spots. ",

author = "D. Beljonne and Jean-Luc Bredas and Cumpston, {B. H.} and J. Ehrlich and L. Erskine and Heikal, {A. A.} and Hu, {Z. Y.} and T. Kogej and Lee, {I. Y.S.} and Marder, {S. R.} and Perry, {J. W.} and H. Rockel and S. Thayumanavan and Wu, {X. L.}",

year = "1997",

month = sep,

day = "1",

language = "English (US)",

volume = "38",

journal = "American Chemical Society, Polymer Preprints, Division of Polymer Chemistry",

issn = "0032-3934",

number = "2",

note = "Proceedings of the 1997 Las Vegas ACS Meeting ; Conference date: 07-09-1997 Through 12-09-1997",

}

TY - JOUR

T1 - Design, synthesis, nonlinear spectroscopy and applications of two-photon absorbing molecules

AU - Beljonne, D.

AU - Bredas, Jean-Luc

AU - Cumpston, B. H.

AU - Ehrlich, J.

AU - Erskine, L.

AU - Heikal, A. A.

AU - Hu, Z. Y.

AU - Kogej, T.

AU - Lee, I. Y.S.

AU - Marder, S. R.

AU - Perry, J. W.

AU - Rockel, H.

AU - Thayumanavan, S.

AU - Wu, X. L.

PY - 1997/9/1

Y1 - 1997/9/1

N2 - Large two-photon absorptivities in bis-donor diphenylpolyene derivatives were observed to determine their two-photon absorption spectra and to examine structure/two-photon spectra relationships. A simple bis donor-substituted stilbene had exceptionally large two-photon absorption cross section. Two-photon excitation of a variety of bis-donor diphenylpolyene derivatives in the presence of acrylate monomers led to the formation of polymers. With the two-photon absorbing molecule dissolved at 1% concentration in triacrylate monomer, an excitation of approximately 600 nm with an intensity of approximately 100 MW/cm 2 yielded cross-linked polymer spots.

AB - Large two-photon absorptivities in bis-donor diphenylpolyene derivatives were observed to determine their two-photon absorption spectra and to examine structure/two-photon spectra relationships. A simple bis donor-substituted stilbene had exceptionally large two-photon absorption cross section. Two-photon excitation of a variety of bis-donor diphenylpolyene derivatives in the presence of acrylate monomers led to the formation of polymers. With the two-photon absorbing molecule dissolved at 1% concentration in triacrylate monomer, an excitation of approximately 600 nm with an intensity of approximately 100 MW/cm 2 yielded cross-linked polymer spots.

UR - http://www.scopus.com/inward/record.url?scp=0031232659&partnerID=8YFLogxK

M3 - Conference article

AN - SCOPUS:0031232659

SN - 0032-3934

VL - 38

JO - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

IS - 2

T2 - Proceedings of the 1997 Las Vegas ACS Meeting

Y2 - 7 September 1997 through 12 September 1997

ER -

Design, synthesis, nonlinear spectroscopy and applications of two-photon absorbing molecules

Abstract

ASJC Scopus subject areas

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