Determination of water activity in ammonium sulfate and sulfuric acid mixtures using levitated single particles

Yong Pyo Kim, Betty K.L. Pun, Chak K. Chan, Richard C. Flagan, John H. Seinfeld

Research output: Contribution to journalArticlepeer-review

37 Scopus citations

Abstract

Water activities of ammonium sulfate-sulfuric acid mixtures with ammonium to sulfate molar ratios between 0 and 2 were measured by a spherical void electrodynamic levitator at relative humidities (RH) of 0.18–0.90. Since the composition of the solid particles is subject to uncertainty, solution properties were determined relative to the known properties at RH about 0.75–0.90. The data were compared with other measurements and the estimates from the Zdanovskii-Stokes-Robinson (ZSR) method and SCAPE, a newly developed gas-particle equilibrium model, and generally were found to be in good agreement. © 1994 Elsevier Science Inc.
Original languageEnglish (US)
Pages (from-to)275-284
Number of pages10
JournalAerosol Science and Technology
Volume20
Issue number3
DOIs
StatePublished - Jan 1 1994
Externally publishedYes

ASJC Scopus subject areas

  • Environmental Chemistry
  • General Materials Science
  • Pollution

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