Diethyl-enetriaminium hexa-fluorido-titanate(IV) fluoride

J. Lhoste, K. Adil*, M. Leblanc, V. Maisonneuve

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

7 Scopus citations


The title compound, (C6H21N4)[TiF6]F, was synthesized by the reaction of TiO2, tris-(2-amino-ethyl)amine, HF and ethanol at 463 K in a microwave oven. The crystal structure consists of two crystallographically independent [TiF6]2- anions, two fluoride anions and two triply-protonated tris-(2-amino-ethyl)-amine cations. The Ti atoms are coordinated by six F atoms within slightly distorted octa-hedra. The anions and cations are connected by inter-molecular N - H⋯F hydrogen bonds.

Original languageEnglish (US)
Pages (from-to)m1375
JournalActa Crystallographica Section E: Structure Reports Online
Issue number11
StatePublished - 2008
Externally publishedYes

ASJC Scopus subject areas

  • General Chemistry
  • General Materials Science
  • Condensed Matter Physics


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