Diethyl-enetriaminium hexa-fluorido-titanate(IV) fluoride

J. Lhoste; K. Adil; M. Leblanc; V. Maisonneuve

doi:10.1107/S1600536808009781

Diethyl-enetriaminium hexa-fluorido-titanate(IV) fluoride

J. Lhoste, K. Adil^*, M. Leblanc, V. Maisonneuve

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The title compound, (C6H21N4)[TiF6]F, was synthesized by the reaction of TiO2, tris-(2-amino-ethyl)amine, HF and ethanol at 463 K in a microwave oven. The crystal structure consists of two crystallographically independent [TiF6]^2- anions, two fluoride anions and two triply-protonated tris-(2-amino-ethyl)-amine cations. The Ti atoms are coordinated by six F atoms within slightly distorted octa-hedra. The anions and cations are connected by inter-molecular N - H⋯F hydrogen bonds.

Original language	English (US)
Pages (from-to)	m1375
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	64
Issue number	11
DOIs	https://doi.org/10.1107/S1600536808009781
State	Published - 2008
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Diethyl-enetriaminium hexa-fluorido-titanate(IV) fluoride",

abstract = "The title compound, (C6H21N4)[TiF6]F, was synthesized by the reaction of TiO2, tris-(2-amino-ethyl)amine, HF and ethanol at 463 K in a microwave oven. The crystal structure consists of two crystallographically independent [TiF6]2- anions, two fluoride anions and two triply-protonated tris-(2-amino-ethyl)-amine cations. The Ti atoms are coordinated by six F atoms within slightly distorted octa-hedra. The anions and cations are connected by inter-molecular N - H⋯F hydrogen bonds.",

author = "J. Lhoste and K. Adil and M. Leblanc and V. Maisonneuve",

year = "2008",

doi = "10.1107/S1600536808009781",

language = "English (US)",

volume = "64",

pages = "m1375",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "11",

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TY - JOUR

T1 - Diethyl-enetriaminium hexa-fluorido-titanate(IV) fluoride

AU - Lhoste, J.

AU - Adil, K.

AU - Leblanc, M.

AU - Maisonneuve, V.

PY - 2008

Y1 - 2008

N2 - The title compound, (C6H21N4)[TiF6]F, was synthesized by the reaction of TiO2, tris-(2-amino-ethyl)amine, HF and ethanol at 463 K in a microwave oven. The crystal structure consists of two crystallographically independent [TiF6]2- anions, two fluoride anions and two triply-protonated tris-(2-amino-ethyl)-amine cations. The Ti atoms are coordinated by six F atoms within slightly distorted octa-hedra. The anions and cations are connected by inter-molecular N - H⋯F hydrogen bonds.

AB - The title compound, (C6H21N4)[TiF6]F, was synthesized by the reaction of TiO2, tris-(2-amino-ethyl)amine, HF and ethanol at 463 K in a microwave oven. The crystal structure consists of two crystallographically independent [TiF6]2- anions, two fluoride anions and two triply-protonated tris-(2-amino-ethyl)-amine cations. The Ti atoms are coordinated by six F atoms within slightly distorted octa-hedra. The anions and cations are connected by inter-molecular N - H⋯F hydrogen bonds.

UR - http://www.scopus.com/inward/record.url?scp=55749090472&partnerID=8YFLogxK

U2 - 10.1107/S1600536808009781

DO - 10.1107/S1600536808009781

M3 - Article

C2 - 21580831

AN - SCOPUS:55749090472

SN - 1600-5368

VL - 64

SP - m1375

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -

Diethyl-enetriaminium hexa-fluorido-titanate(IV) fluoride

Abstract

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