TY - JOUR
T1 - Dimensionality Mediated Highly Repeatable and Fast Transformation of Coordination Polymer Single Crystals for All-Optical Data Processing
AU - Kulachenkov, Nikita
AU - Barsukova, Marina
AU - Alekseevskiy, Pavel
AU - Sapianik, Aleksandr A.
AU - Sergeev, Maxim
AU - Yankin, Andrei
AU - Krasilin, Andrei A.
AU - Bachinin, Semyon
AU - Shipilovskikh, Sergei
AU - Poturaev, Petr
AU - Medvedeva, Natalia
AU - Denislamova, Ekaterina
AU - Zelenovskiy, Pavel S.
AU - Shilovskikh, Vladimir V.
AU - Kenzhebayeva, Yuliya
AU - Efimova, Anastasiia
AU - Novikov, Alexander S.
AU - Lunev, Artem
AU - Fedin, Vladimir P.
AU - Milichko, Valentin A.
N1 - Funding Information:
V.A.M. acknowledges financial support from the Russian Science Foundation (Project “Metal-organic frameworks: New class of crystals for data storage and processing” No. 19-79-10241) for optical experiments. P.S.Z. is grateful to the Ural Center for Shared Use “Modern nanotechnology” Ural Federal University (Reg. numb. 2968) supported by the Ministry of Science and Higher Education of the Russian Federation (Projec numb. 075-15-2021-677). The instrumental resources were partly provided by the the Centre for X-ray Diffraction Studies and Geomodel Resource Center of Saint Petersburg State University. The authors acknowledge A. Potapov (Nikolaev Institute of Inorganic Chemistry SB RAS, Russia) for synthesis support, Bartłomiej M. Szyja (Faculty of Chemistry, Wrocław University of Science and Technology, Wrocław, Poland), and Evgeny A. Pidko (Inorganic Systems Engineering Group, Department of Chemical Engineering, Delft University of Technology, The Netherlands) and supercomputer facilities from NWO Domain Science for their contribution to numerical modeling. The research was supported by Priority 2030 Federal Academic Leadership Program (A.S.N. is grateful to the RUDN University Strategic Academic Leadership Program, V.A.M. is grateful to ITMO University Strategic Academic Leadership Program).
Publisher Copyright:
© 2022 American Chemical Society. All rights reserved.
PY - 2022/9/14
Y1 - 2022/9/14
N2 - A family of coordination polymers (CPs) based on dynamic structural elements are of great fundamental and commercial interest addressing modern problems in controlled molecular separation, catalysis, and even data processing. Herein, the endurance and fast structural dynamics of such materials at ambient conditions are still a fundamental challenge. Here, we report on the design of a series of Cu-based CPs [Cu(bImB)Cl2] and [Cu(bImB)2Cl2] with flexible ligand bImB (1,4-bis(imidazol-1-yl)butane) packed into one- and two-dimensional (1D, 2D) structures demonstrating dimensionality mediated flexibility and reversible structural transformations. Using the laser pulses as a fast source of activation energy, we initiate CP heating followed by anisotropic thermal expansion and 0.2-0.8% volume changes with the record transformation rates from 2220 to 1640 s-1for 1D and 2D CPs, respectively. The endurance over 103cycles of structural transformations, achieved for the CPs at ambient conditions, allows demonstrating optical fiber integrated all-optical data processing.
AB - A family of coordination polymers (CPs) based on dynamic structural elements are of great fundamental and commercial interest addressing modern problems in controlled molecular separation, catalysis, and even data processing. Herein, the endurance and fast structural dynamics of such materials at ambient conditions are still a fundamental challenge. Here, we report on the design of a series of Cu-based CPs [Cu(bImB)Cl2] and [Cu(bImB)2Cl2] with flexible ligand bImB (1,4-bis(imidazol-1-yl)butane) packed into one- and two-dimensional (1D, 2D) structures demonstrating dimensionality mediated flexibility and reversible structural transformations. Using the laser pulses as a fast source of activation energy, we initiate CP heating followed by anisotropic thermal expansion and 0.2-0.8% volume changes with the record transformation rates from 2220 to 1640 s-1for 1D and 2D CPs, respectively. The endurance over 103cycles of structural transformations, achieved for the CPs at ambient conditions, allows demonstrating optical fiber integrated all-optical data processing.
KW - Coordination polymers
KW - data processing
KW - flexibility
KW - in situ spectroscopy
KW - low-dimensional structures
KW - structural transformation
UR - http://www.scopus.com/inward/record.url?scp=85137291257&partnerID=8YFLogxK
U2 - 10.1021/acs.nanolett.2c01770
DO - 10.1021/acs.nanolett.2c01770
M3 - Article
C2 - 36018814
AN - SCOPUS:85137291257
SN - 1530-6984
VL - 22
SP - 6972
EP - 6981
JO - Nano Letters
JF - Nano Letters
IS - 17
ER -