Direct catalytic azidation of allylic alcohols

Magnus Rueping; Carlos Vila; Uxue Uria

doi:10.1021/ol203310h

Direct catalytic azidation of allylic alcohols

Magnus Rueping^*, Carlos Vila, Uxue Uria

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

49 Scopus citations

Abstract

A direct catalytic azidation of primary, secondary, and tertiary allylic alcohols has been developed. This new azidation reaction affords the corresponding allylic azides in high to excellent yields and regioselectivities. The reaction provides straightforward access to allylic azides that are valuable intermediates in organic synthesis, including the preparation of primary amines or 1,2,3-triazole derivatives.

Original language	English (US)
Pages (from-to)	768-771
Number of pages	4
Journal	Organic Letters
Volume	14
Issue number	3
DOIs	https://doi.org/10.1021/ol203310h
State	Published - Feb 3 2012
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol203310h

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@article{4098572a81064e2caa12a774d20361f5,

title = "Direct catalytic azidation of allylic alcohols",

abstract = "A direct catalytic azidation of primary, secondary, and tertiary allylic alcohols has been developed. This new azidation reaction affords the corresponding allylic azides in high to excellent yields and regioselectivities. The reaction provides straightforward access to allylic azides that are valuable intermediates in organic synthesis, including the preparation of primary amines or 1,2,3-triazole derivatives.",

author = "Magnus Rueping and Carlos Vila and Uxue Uria",

year = "2012",

month = feb,

day = "3",

doi = "10.1021/ol203310h",

language = "English (US)",

volume = "14",

pages = "768--771",

journal = "Organic Letters",

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publisher = "American Chemical Society",

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TY - JOUR

T1 - Direct catalytic azidation of allylic alcohols

AU - Rueping, Magnus

AU - Vila, Carlos

AU - Uria, Uxue

PY - 2012/2/3

Y1 - 2012/2/3

N2 - A direct catalytic azidation of primary, secondary, and tertiary allylic alcohols has been developed. This new azidation reaction affords the corresponding allylic azides in high to excellent yields and regioselectivities. The reaction provides straightforward access to allylic azides that are valuable intermediates in organic synthesis, including the preparation of primary amines or 1,2,3-triazole derivatives.

AB - A direct catalytic azidation of primary, secondary, and tertiary allylic alcohols has been developed. This new azidation reaction affords the corresponding allylic azides in high to excellent yields and regioselectivities. The reaction provides straightforward access to allylic azides that are valuable intermediates in organic synthesis, including the preparation of primary amines or 1,2,3-triazole derivatives.

UR - http://www.scopus.com/inward/record.url?scp=84856695563&partnerID=8YFLogxK

U2 - 10.1021/ol203310h

DO - 10.1021/ol203310h

M3 - Article

C2 - 22256853

AN - SCOPUS:84856695563

SN - 1523-7060

VL - 14

SP - 768

EP - 771

JO - Organic Letters

JF - Organic Letters

IS - 3

ER -

Direct catalytic azidation of allylic alcohols

Abstract

ASJC Scopus subject areas

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