A trifunctional single-site catalyst: Ethylene is selectively transformed into propylene in a continuous-flow reactor in the presence of the supported tungsten hydride W(H)3/Al2O3. Since the catalyst is also active for olefin metathesis, the reaction is likely to proceed at a "trifunctional catalytic site" by ethylene dimerization, butene isomerization, and cross-metathesis of ethylene with 2-butenes (see picture). (Chemical Equation Presented).
|Original language||English (US)|
|Number of pages||4|
|Journal||Angewandte Chemie - International Edition|
|State||Published - 2007|
- Supported catalysts
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