TY - JOUR
T1 - Dual-Function Conductive Copper Hollow Fibers for Microfiltration and Anti-biofouling in Electrochemical Membrane Bioreactors
AU - Liu, Defei
AU - Chen, Xin
AU - Bian, Bin
AU - Lai, Zhiping
AU - Situ, Yue
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: Funding: The authors are grateful for financial support from King Abdullah University of Science and Technology (KAUST) and Foshan University. Acknowledgments: DL is grateful for kind help from Dr. Yuanlie Yu and Dr. Yang Liu from AMPM center, KAUST. BB is grateful for kind advice from Dr. Pascal Saikaly and Dr. Krishna Katuri from Water Desalination and Reuse Center, KAUST.
PY - 2018/9/25
Y1 - 2018/9/25
N2 - Membrane bioreactors (MBRs) with polymeric/ceramic microfiltration (MF) membranes have been commonly used for wastewater treatment today. However, membrane biofouling often results in a dramatically-reduced service life of MF membranes, which limits the application of this technology. In this study, Cu hollow fiber membranes (Cu-HFMs) with low resistivity (104.8–309.8 nΩ·m) and anti-biofouling properties were successfully synthesized. Further analysis demonstrated that Cu-HFMs reduced at 625°C achieved the bimodal pore size distribution of ~1 μm and a porosity of 46%, which enable high N2 permeance (1.56 × 10−5 mol/m2 s pa) and pure water flux (5812 LMH/bar). The Cu-HFMs were further applied as the conductive cathodes, as well as MF membranes, in the electrochemical membrane bioreactor (EMBR) system that was enriched with domestic wastewater at an applied voltage of 0.9 V. Excellent permeate quality (Total suspended solids (TSS) = 11 mg/L) was achieved at a flux of 9.47 LMH after Cu-HFM filtration, with relatively stable transmembrane pressure (TMP) and low Cu2+ dissolvability (
AB - Membrane bioreactors (MBRs) with polymeric/ceramic microfiltration (MF) membranes have been commonly used for wastewater treatment today. However, membrane biofouling often results in a dramatically-reduced service life of MF membranes, which limits the application of this technology. In this study, Cu hollow fiber membranes (Cu-HFMs) with low resistivity (104.8–309.8 nΩ·m) and anti-biofouling properties were successfully synthesized. Further analysis demonstrated that Cu-HFMs reduced at 625°C achieved the bimodal pore size distribution of ~1 μm and a porosity of 46%, which enable high N2 permeance (1.56 × 10−5 mol/m2 s pa) and pure water flux (5812 LMH/bar). The Cu-HFMs were further applied as the conductive cathodes, as well as MF membranes, in the electrochemical membrane bioreactor (EMBR) system that was enriched with domestic wastewater at an applied voltage of 0.9 V. Excellent permeate quality (Total suspended solids (TSS) = 11 mg/L) was achieved at a flux of 9.47 LMH after Cu-HFM filtration, with relatively stable transmembrane pressure (TMP) and low Cu2+ dissolvability (
UR - http://hdl.handle.net/10754/628799
UR - https://www.frontiersin.org/articles/10.3389/fchem.2018.00445/full
U2 - 10.3389/fchem.2018.00445
DO - 10.3389/fchem.2018.00445
M3 - Article
C2 - 30320076
SN - 2296-2646
VL - 6
JO - Frontiers in Chemistry
JF - Frontiers in Chemistry
ER -