TY - JOUR
T1 - Effect of NiAl2O4 Formation on Ni/Al2O3 Stability during Dry Reforming of Methane
AU - Zhou, Lu
AU - Li, Lidong
AU - Wei, Nini
AU - Li, Jun
AU - Basset, Jean-Marie
N1 - KAUST Repository Item: Exported on 2020-10-01
PY - 2015/7/16
Y1 - 2015/7/16
N2 - A series of alumina-supported Ni catalysts were prepared to examine their activity and carbon deposition during dry reforming of methane (DRM). With an increase in the final calcination temperature to T=900 °C to form exclusively NiAl2O4, a catalyst with strong metal–support interactions was obtained. During a long-term DRM reaction (of about t=100 h) at T=700 °C and with CH4/CO2=1:1, reduced Ni (from NiAl2O4) showed a high resistance to sintering and coking. The DRM kinetics behaviors of the catalysts calcined at different temperatures were also investigated. Carbon growth models were proposed to rationalize the different carbon morphologies observed on the catalysts.
AB - A series of alumina-supported Ni catalysts were prepared to examine their activity and carbon deposition during dry reforming of methane (DRM). With an increase in the final calcination temperature to T=900 °C to form exclusively NiAl2O4, a catalyst with strong metal–support interactions was obtained. During a long-term DRM reaction (of about t=100 h) at T=700 °C and with CH4/CO2=1:1, reduced Ni (from NiAl2O4) showed a high resistance to sintering and coking. The DRM kinetics behaviors of the catalysts calcined at different temperatures were also investigated. Carbon growth models were proposed to rationalize the different carbon morphologies observed on the catalysts.
UR - http://hdl.handle.net/10754/567060
UR - http://doi.wiley.com/10.1002/cctc.201500379
UR - http://www.scopus.com/inward/record.url?scp=84939256413&partnerID=8YFLogxK
U2 - 10.1002/cctc.201500379
DO - 10.1002/cctc.201500379
M3 - Article
SN - 1867-3880
VL - 7
SP - 2508
EP - 2516
JO - ChemCatChem
JF - ChemCatChem
IS - 16
ER -