Effect of shear stress within the spinneret on hollow fiber membrane morphology and separation performance

Tai Shung Chung; Soo Khean Teoh; Wayne W.Y. Lau; M. P. Srinivasan

doi:10.1021/ie9802111

Effect of shear stress within the spinneret on hollow fiber membrane morphology and separation performance

Tai Shung Chung^*, Soo Khean Teoh, Wayne W.Y. Lau, M. P. Srinivasan

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

73 Scopus citations

Abstract

The effects of shear stress on the morphology and gas separation performance of hollow fiber membranes were investigated. The hollow fiber membranes spun with large die length to flow channel gap ratio with high shear exhibited tighter molecular packing structure and higher selectivity. Hollow fibers spun with high shear rate have lower thermal expansion coefficient and higher loss modulus. The fully developed high shear stress within the spinneret altered the thermodynamics of nodular formation of the hollow fiber membranes.

Original language	English (US)
Pages (from-to)	3930-3938
Number of pages	9
Journal	Industrial and Engineering Chemistry Research
Volume	37
Issue number	10
DOIs	https://doi.org/10.1021/ie9802111
State	Published - 1998
Externally published	Yes

Keywords

Fiber membrane
Morphology

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering

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10.1021/ie9802111

Cite this

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title = "Effect of shear stress within the spinneret on hollow fiber membrane morphology and separation performance",

abstract = "The effects of shear stress on the morphology and gas separation performance of hollow fiber membranes were investigated. The hollow fiber membranes spun with large die length to flow channel gap ratio with high shear exhibited tighter molecular packing structure and higher selectivity. Hollow fibers spun with high shear rate have lower thermal expansion coefficient and higher loss modulus. The fully developed high shear stress within the spinneret altered the thermodynamics of nodular formation of the hollow fiber membranes.",

keywords = "Fiber membrane, Morphology",

author = "Chung, {Tai Shung} and Teoh, {Soo Khean} and Lau, {Wayne W.Y.} and Srinivasan, {M. P.}",

year = "1998",

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journal = "Industrial and Engineering Chemistry Research",

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AU - Chung, Tai Shung

AU - Teoh, Soo Khean

AU - Lau, Wayne W.Y.

AU - Srinivasan, M. P.

PY - 1998

Y1 - 1998

N2 - The effects of shear stress on the morphology and gas separation performance of hollow fiber membranes were investigated. The hollow fiber membranes spun with large die length to flow channel gap ratio with high shear exhibited tighter molecular packing structure and higher selectivity. Hollow fibers spun with high shear rate have lower thermal expansion coefficient and higher loss modulus. The fully developed high shear stress within the spinneret altered the thermodynamics of nodular formation of the hollow fiber membranes.

AB - The effects of shear stress on the morphology and gas separation performance of hollow fiber membranes were investigated. The hollow fiber membranes spun with large die length to flow channel gap ratio with high shear exhibited tighter molecular packing structure and higher selectivity. Hollow fibers spun with high shear rate have lower thermal expansion coefficient and higher loss modulus. The fully developed high shear stress within the spinneret altered the thermodynamics of nodular formation of the hollow fiber membranes.

KW - Fiber membrane

KW - Morphology

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U2 - 10.1021/ie9802111

DO - 10.1021/ie9802111

M3 - Article

AN - SCOPUS:0032194508

SN - 0888-5885

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JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

IS - 10

ER -

Effect of shear stress within the spinneret on hollow fiber membrane morphology and separation performance

Abstract

Keywords

ASJC Scopus subject areas

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