TY - JOUR
T1 - Efficient CO2/N2 and CO2/CH4 separation using NH2-MIL-53(Al)/cellulose acetate (CA) mixed matrix membranes
AU - Mubashir, Muhammad
AU - Yeong, Yin Fong
AU - Lau, Kok Keong
AU - Chew, Thiam Leng
AU - Norwahyu, Jusoh
N1 - Generated from Scopus record by KAUST IRTS on 2023-09-20
PY - 2018/6/30
Y1 - 2018/6/30
N2 - In the current study, new types of MMMs are fabricated by incorporating NH2-MIL-53(Al) filler into cellulose acetate (CA) polymer. Subsequently, crystallinity, morphology, thermal stability, functional groups and density measurement of the resultant MMMs were verified by using different analytical tools. The results showed that the presence of NH2-MIL-53(Al) in CA matrix had enhanced the CO2 permeability, CO2/N2 and CO2/CH4 ideal selectivities from 15.5 Barrer to 52.6 Barrer, 8.8 to 23.4 and 10.7 to 28.7, respectively. The present study revealed that the addition of 15 wt% NH2-MIL-53(Al) MOF into the CA matrix resulted in highest enhancement of FFV. Furthermore, MMM loaded with 15 wt% NH2-MIL-53(Al) demonstrated highest CO2 permeability as well as CO2/CH4 and CO2/N2 selectivities of 52.6 Barrer, 28.7 and 23.4, respectively. Besides, the resultant MMM showed CO2 plasticization resistance of up to 30 bar, which is 200% increment in comparison of pristine CA membrane which is only 10 bar. This work also revealed that the resultant MMMs showed significantly higher CO2 separation performance compared to the results previously reported for CA-based MMMs. Thus, it can be concluded that the MMMs fabricated in the present work has potential for CO2 removal from the flue gas and natural gas at industrial scale.
AB - In the current study, new types of MMMs are fabricated by incorporating NH2-MIL-53(Al) filler into cellulose acetate (CA) polymer. Subsequently, crystallinity, morphology, thermal stability, functional groups and density measurement of the resultant MMMs were verified by using different analytical tools. The results showed that the presence of NH2-MIL-53(Al) in CA matrix had enhanced the CO2 permeability, CO2/N2 and CO2/CH4 ideal selectivities from 15.5 Barrer to 52.6 Barrer, 8.8 to 23.4 and 10.7 to 28.7, respectively. The present study revealed that the addition of 15 wt% NH2-MIL-53(Al) MOF into the CA matrix resulted in highest enhancement of FFV. Furthermore, MMM loaded with 15 wt% NH2-MIL-53(Al) demonstrated highest CO2 permeability as well as CO2/CH4 and CO2/N2 selectivities of 52.6 Barrer, 28.7 and 23.4, respectively. Besides, the resultant MMM showed CO2 plasticization resistance of up to 30 bar, which is 200% increment in comparison of pristine CA membrane which is only 10 bar. This work also revealed that the resultant MMMs showed significantly higher CO2 separation performance compared to the results previously reported for CA-based MMMs. Thus, it can be concluded that the MMMs fabricated in the present work has potential for CO2 removal from the flue gas and natural gas at industrial scale.
UR - https://linkinghub.elsevier.com/retrieve/pii/S1383586617335165
UR - http://www.scopus.com/inward/record.url?scp=85041392597&partnerID=8YFLogxK
U2 - 10.1016/j.seppur.2018.01.038
DO - 10.1016/j.seppur.2018.01.038
M3 - Article
SN - 1873-3794
VL - 199
SP - 140
EP - 151
JO - Separation and Purification Technology
JF - Separation and Purification Technology
ER -