TY - JOUR
T1 - Efficient Pd@MIL-101(Cr) hetero-catalysts for 2-butyne-1,4-diol hydrogenation exhibiting high selectivity
AU - Yin, Dongdong
AU - Li, Chuang
AU - Ren, Hangxing
AU - Shekhah, Osama
AU - Liu, Jinxuan
AU - Liang, Changhai
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: We gratefully acknowledge the financial support provided by the National Natural Science Foundation of China (21673032, 21573031 and 21428301) and the Fundamental Research Funds for the Central Universities (DUT15ZD106 and DUT15RC(4)09).
PY - 2017
Y1 - 2017
N2 - Pd@MIL-101(Cr) hetero-catalysts have been successfully prepared using the metal-organic chemical vapour deposition (MOCVD) approach, by choosing [Pd(η-CH)(η-CH)] as a volatile precursor, and the hydrothermally stable metal-organic framework, MIL-101(Cr) as a support. The prepared Pd@MIL-101(Cr) hetero-catalysts characterized with various analytical techniques, exhibited highly monodispersed immobilized Pd nanoparticles in the MIL-101(Cr) cavities, while retaining the pristine crystallinity and porosity. The intact hybrid Pd@MIL-101(Cr) has been demonstrated to be an efficient catalyst for 2-butyne-1,4-diol hydrogenation with excellent activity, stability and selectivity (2-butene-1,4-diol (>94%)).
AB - Pd@MIL-101(Cr) hetero-catalysts have been successfully prepared using the metal-organic chemical vapour deposition (MOCVD) approach, by choosing [Pd(η-CH)(η-CH)] as a volatile precursor, and the hydrothermally stable metal-organic framework, MIL-101(Cr) as a support. The prepared Pd@MIL-101(Cr) hetero-catalysts characterized with various analytical techniques, exhibited highly monodispersed immobilized Pd nanoparticles in the MIL-101(Cr) cavities, while retaining the pristine crystallinity and porosity. The intact hybrid Pd@MIL-101(Cr) has been demonstrated to be an efficient catalyst for 2-butyne-1,4-diol hydrogenation with excellent activity, stability and selectivity (2-butene-1,4-diol (>94%)).
UR - http://hdl.handle.net/10754/622725
UR - http://pubs.rsc.org/en/Content/ArticleLanding/2017/RA/C6RA25722D#!divAbstract
UR - http://www.scopus.com/inward/record.url?scp=85009289160&partnerID=8YFLogxK
U2 - 10.1039/c6ra25722d
DO - 10.1039/c6ra25722d
M3 - Article
SN - 2046-2069
VL - 7
SP - 1626
EP - 1633
JO - RSC Adv.
JF - RSC Adv.
IS - 3
ER -