Electrocatalytic Reduction of Carbon Dioxide with a Well-Defined PN3-Ru Pincer Complex

Shixiong Min; Shahid Rasul; Huaifeng Li; David C. Grills; Kazuhiro Takanabe; Lain-Jong Li; Kuo-Wei Huang

doi:10.1002/cplu.201500474

Electrocatalytic Reduction of Carbon Dioxide with a Well-Defined PN3-Ru Pincer Complex

Shixiong Min, Shahid Rasul, Huaifeng Li, David C. Grills, Kazuhiro Takanabe, Lain-Jong Li, Kuo-Wei Huang

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

A well-defined PN3-Ru pincer complex (5) bearing a redox-active bipyridine ligand with an aminophosphine arm has been established as an effective and stable molecular electrocatalyst for CO2 reduction to CO and HCOOH with negligible formation of H2 in a H2O/MeCN mixture. Done in a pin A PN3-Ru pincer complex (see figure) has been found to show high activity and stability as a molecular electrocatalyst for CO2 reduction to CO and HCOOH in MeCN/H2O.

Original language	English (US)
Pages (from-to)	166-171
Number of pages	6
Journal	ChemPlusChem
Volume	81
Issue number	2
DOIs	https://doi.org/10.1002/cplu.201500474
State	Published - Nov 13 2015

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abstract = "A well-defined PN3-Ru pincer complex (5) bearing a redox-active bipyridine ligand with an aminophosphine arm has been established as an effective and stable molecular electrocatalyst for CO2 reduction to CO and HCOOH with negligible formation of H2 in a H2O/MeCN mixture. Done in a pin A PN3-Ru pincer complex (see figure) has been found to show high activity and stability as a molecular electrocatalyst for CO2 reduction to CO and HCOOH in MeCN/H2O.",

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AU - Min, Shixiong

AU - Rasul, Shahid

AU - Li, Huaifeng

AU - Grills, David C.

AU - Takanabe, Kazuhiro

AU - Li, Lain-Jong

AU - Huang, Kuo-Wei

N1 - KAUST Repository Item: Exported on 2020-10-01

PY - 2015/11/13

Y1 - 2015/11/13

N2 - A well-defined PN3-Ru pincer complex (5) bearing a redox-active bipyridine ligand with an aminophosphine arm has been established as an effective and stable molecular electrocatalyst for CO2 reduction to CO and HCOOH with negligible formation of H2 in a H2O/MeCN mixture. Done in a pin A PN3-Ru pincer complex (see figure) has been found to show high activity and stability as a molecular electrocatalyst for CO2 reduction to CO and HCOOH in MeCN/H2O.

AB - A well-defined PN3-Ru pincer complex (5) bearing a redox-active bipyridine ligand with an aminophosphine arm has been established as an effective and stable molecular electrocatalyst for CO2 reduction to CO and HCOOH with negligible formation of H2 in a H2O/MeCN mixture. Done in a pin A PN3-Ru pincer complex (see figure) has been found to show high activity and stability as a molecular electrocatalyst for CO2 reduction to CO and HCOOH in MeCN/H2O.

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JF - ChemPlusChem

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Electrocatalytic Reduction of Carbon Dioxide with a Well-Defined PN3-Ru Pincer Complex

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