Electrochemical Stability and Ambipolar Charge Transport in Diketopyrrolopyrrole-Based Organic Materials

Suman Ray, Julianna Panidi, Tushita Mukhopadhyay, Ulrike Salzner, Thomas D. Anthopoulos, Satish Patil

Research output: Contribution to journalArticlepeer-review

5 Scopus citations


An important strategy for realizing flexible complementary circuits with organic semiconductors is to achieve balanced ambipolar charge transport properties with reduced anisotropy. Here, we present a series of star-shaped diketopyrrolopyrrole (DPP)-based organic materials synthesized for improved intermolecular charge transport while retaining the ambipolar charge transport properties of their linear counterparts. Steady-state UV–visible spectroscopic studies confirm that the oligomers are highly aggregated in the thin film as evidenced from appearance of prominent vibronic features and red-shifted absorption bands. Ambipolar transport properties of these materials were verified in organic field-effect transistors (OFETs). The results show that the star-shaped DPP systems have the potential to outperform their linear counterparts in devices.
Original languageEnglish (US)
Pages (from-to)2037-2046
Number of pages10
JournalACS Applied Electronic Materials
Issue number10
StatePublished - Sep 3 2019


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