Electronic structure of poly(9,9-dioctylfluorene) in the pristine and reduced state

G. Greczynski, M. Fahlman, W. R. Salaneck, N. Johansson, D. A. Dos Santos, A. Dkhissi, Jean-Luc Bredas*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

9 Scopus citations


The electronic structure of a polymer of interest in polymer-based light emitting devices, poly(9,9-dioctyl-fluorene), was studied using a combined experimental-theoretical approach. Results were compared with those of equivalent studies of the electronic structure of two related conjugated polymers: poly(p-phenylene) and a latter-type poly (p-phenylene) (LPPP). Finally, it was shown that electrons added to the polymer system lead to the formation of polarons at low doping levels, and bipolarons at high doping levels. The energies of the polaron and bipolaron states were measured directly, and agree with the theoretical modeling of the added electrons.

Original languageEnglish (US)
Pages (from-to)1700-1706
Number of pages7
JournalJournal of Chemical Physics
Issue number4
StatePublished - Jan 22 2002

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry


Dive into the research topics of 'Electronic structure of poly(9,9-dioctylfluorene) in the pristine and reduced state'. Together they form a unique fingerprint.

Cite this