Electronic structure tuning of new fused thieno[3,2-b]thieno bisthiophene based polymers via alkyl chain and Group IV heteroatom modulation

Bob C. Schroeder; Hugo Bronstein; Raja Shahid Ashraf; Weimin Zhang; Zhenggang Huang; Pabitra Shakya Tuladhar; Thomas D. Anthopoulos; James R. Durrant; Iain McCulloch

doi:10.1117/12.929622

Electronic structure tuning of new fused thieno[3,2-b]thieno bisthiophene based polymers via alkyl chain and Group IV heteroatom modulation

Bob C. Schroeder^*, Hugo Bronstein, Raja Shahid Ashraf, Weimin Zhang, Zhenggang Huang, Pabitra Shakya Tuladhar, Thomas D. Anthopoulos, James R. Durrant, Iain McCulloch

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

Herein we present an extension of our work on indacenodithiophenes (IDT) by replacing the central benzene ring with a thieno(3,2-b) thiophene unit. This newly developed thieno[3,2-b]thieno bisthiophene (4T) donor moiety was synthesized from commercially available reagents and incorporated into a series of donor-acceptor polymers. We will discuss the pronounced donating character of 4T compared to IDT and the choice of bridging atom in those new polymers with an emphasis on field effect transistor and photovoltaic device performance.

Original language	English (US)
Title of host publication	Organic Photovoltaics XIII
DOIs	https://doi.org/10.1117/12.929622
State	Published - 2012
Externally published	Yes
Event	Organic Photovoltaics XIII - San Diego, CA, United States Duration: Aug 14 2012 → Aug 16 2012

Publication series

Name	Proceedings of SPIE - The International Society for Optical Engineering
Volume	8477
ISSN (Print)	0277-786X

Other

Other	Organic Photovoltaics XIII
Country/Territory	United States
City	San Diego, CA
Period	08/14/12 → 08/16/12

Keywords

Field effect transistor
Heteroatom
Indacenodithiophene
Organic solar cell
Thieno(3,2-b) thiophene

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Computer Science Applications
Applied Mathematics
Electrical and Electronic Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1117/12.929622

Cite this

Schroeder, B. C., Bronstein, H., Ashraf, R. S., Zhang, W., Huang, Z., Tuladhar, P. S., Anthopoulos, T. D., Durrant, J. R., & McCulloch, I. (2012). Electronic structure tuning of new fused thieno[3,2-b]thieno bisthiophene based polymers via alkyl chain and Group IV heteroatom modulation. In Organic Photovoltaics XIII Article 847709 (Proceedings of SPIE - The International Society for Optical Engineering; Vol. 8477). https://doi.org/10.1117/12.929622

@inproceedings{c1fe4e2ffabf4c8895fe6ebb08193770,

title = "Electronic structure tuning of new fused thieno[3,2-b]thieno bisthiophene based polymers via alkyl chain and Group IV heteroatom modulation",

abstract = "Herein we present an extension of our work on indacenodithiophenes (IDT) by replacing the central benzene ring with a thieno(3,2-b) thiophene unit. This newly developed thieno[3,2-b]thieno bisthiophene (4T) donor moiety was synthesized from commercially available reagents and incorporated into a series of donor-acceptor polymers. We will discuss the pronounced donating character of 4T compared to IDT and the choice of bridging atom in those new polymers with an emphasis on field effect transistor and photovoltaic device performance.",

keywords = "Field effect transistor, Heteroatom, Indacenodithiophene, Organic solar cell, Thieno(3,2-b) thiophene",

author = "Schroeder, {Bob C.} and Hugo Bronstein and Ashraf, {Raja Shahid} and Weimin Zhang and Zhenggang Huang and Tuladhar, {Pabitra Shakya} and Anthopoulos, {Thomas D.} and Durrant, {James R.} and Iain McCulloch",

year = "2012",

doi = "10.1117/12.929622",

language = "English (US)",

isbn = "9780819491947",

series = "Proceedings of SPIE - The International Society for Optical Engineering",

booktitle = "Organic Photovoltaics XIII",

note = "Organic Photovoltaics XIII ; Conference date: 14-08-2012 Through 16-08-2012",

}

Schroeder, BC, Bronstein, H, Ashraf, RS, Zhang, W, Huang, Z, Tuladhar, PS, Anthopoulos, TD, Durrant, JR & McCulloch, I 2012, Electronic structure tuning of new fused thieno[3,2-b]thieno bisthiophene based polymers via alkyl chain and Group IV heteroatom modulation. in Organic Photovoltaics XIII., 847709, Proceedings of SPIE - The International Society for Optical Engineering, vol. 8477, Organic Photovoltaics XIII, San Diego, CA, United States, 08/14/12. https://doi.org/10.1117/12.929622

Electronic structure tuning of new fused thieno[3,2-b]thieno bisthiophene based polymers via alkyl chain and Group IV heteroatom modulation. / Schroeder, Bob C.; Bronstein, Hugo; Ashraf, Raja Shahid et al.
Organic Photovoltaics XIII. 2012. 847709 (Proceedings of SPIE - The International Society for Optical Engineering; Vol. 8477).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Electronic structure tuning of new fused thieno[3,2-b]thieno bisthiophene based polymers via alkyl chain and Group IV heteroatom modulation

AU - Schroeder, Bob C.

AU - Bronstein, Hugo

AU - Ashraf, Raja Shahid

AU - Zhang, Weimin

AU - Huang, Zhenggang

AU - Tuladhar, Pabitra Shakya

AU - Anthopoulos, Thomas D.

AU - Durrant, James R.

AU - McCulloch, Iain

PY - 2012

Y1 - 2012

N2 - Herein we present an extension of our work on indacenodithiophenes (IDT) by replacing the central benzene ring with a thieno(3,2-b) thiophene unit. This newly developed thieno[3,2-b]thieno bisthiophene (4T) donor moiety was synthesized from commercially available reagents and incorporated into a series of donor-acceptor polymers. We will discuss the pronounced donating character of 4T compared to IDT and the choice of bridging atom in those new polymers with an emphasis on field effect transistor and photovoltaic device performance.

AB - Herein we present an extension of our work on indacenodithiophenes (IDT) by replacing the central benzene ring with a thieno(3,2-b) thiophene unit. This newly developed thieno[3,2-b]thieno bisthiophene (4T) donor moiety was synthesized from commercially available reagents and incorporated into a series of donor-acceptor polymers. We will discuss the pronounced donating character of 4T compared to IDT and the choice of bridging atom in those new polymers with an emphasis on field effect transistor and photovoltaic device performance.

KW - Field effect transistor

KW - Heteroatom

KW - Indacenodithiophene

KW - Organic solar cell

KW - Thieno(3,2-b) thiophene

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U2 - 10.1117/12.929622

DO - 10.1117/12.929622

M3 - Conference contribution

AN - SCOPUS:84872141873

SN - 9780819491947

T3 - Proceedings of SPIE - The International Society for Optical Engineering

BT - Organic Photovoltaics XIII

T2 - Organic Photovoltaics XIII

Y2 - 14 August 2012 through 16 August 2012

ER -

Electronic structure tuning of new fused thieno[3,2-b]thieno bisthiophene based polymers via alkyl chain and Group IV heteroatom modulation

Abstract

Publication series

Other

Keywords

ASJC Scopus subject areas

UN SDGs

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