TY - JOUR
T1 - Entropy–enthalpy compensation as a fundamental concept and analysis tool for systematical experimental data
AU - Starikov, E.B.
AU - Nordén, B.
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: B.N. would like to acknowledge financial support from King Abdullah University of Science and Technology (KAUST).
This publication acknowledges KAUST support, but has no KAUST affiliated authors.
PY - 2012/6
Y1 - 2012/6
N2 - Enthalpy-entropy compensation (EEC) has a definite physical sense. Here, we review EEC from a new standpoint, using the notion of correlation. The latter has two basic meanings: (a) 'A' is correlated to 'B' means 'A' results from 'B' or vice versa; (b) this same means there is some real, but hidden 'C' in connection to both 'A' and 'B'). In accordance with the interpretation (b), we try rationalizing EEC in terms of hidden, but physically real factors. © 2012 Elsevier B.V. All rights reserved.
AB - Enthalpy-entropy compensation (EEC) has a definite physical sense. Here, we review EEC from a new standpoint, using the notion of correlation. The latter has two basic meanings: (a) 'A' is correlated to 'B' means 'A' results from 'B' or vice versa; (b) this same means there is some real, but hidden 'C' in connection to both 'A' and 'B'). In accordance with the interpretation (b), we try rationalizing EEC in terms of hidden, but physically real factors. © 2012 Elsevier B.V. All rights reserved.
UR - http://hdl.handle.net/10754/598204
UR - https://linkinghub.elsevier.com/retrieve/pii/S000926141200509X
UR - http://www.scopus.com/inward/record.url?scp=84861571174&partnerID=8YFLogxK
U2 - 10.1016/j.cplett.2012.04.028
DO - 10.1016/j.cplett.2012.04.028
M3 - Article
SN - 0009-2614
VL - 538
SP - 118
EP - 120
JO - Chemical Physics Letters
JF - Chemical Physics Letters
ER -