Exploring the multifunctionality in metal-organic framework materials: How do the stilbenedicarboxylate and imidazolyl ligands tune the characteristics of coordination polymers?

Marina O. Barsukova, Sergey A. Sapchenko*, Konstantin A. Kovalenko, Denis G. Samsonenko, Andrei S. Potapov, Danil N. Dybtsev, Vladimir P. Fedin

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    22 Scopus citations

    Abstract

    Six isoreticular metal-organic frameworks (MOFs) based on zinc, cadmium and cobalt ions, 4,4′-stilbenedicarboxylic acid and the flexible ligands 1,4-bis(imidazol-1-yl)butane and 1,6-bis(imidazol-1-yl)hexane were prepared. The synergistic effect coming from the assembly of stilbenedicarboxylate and imidazolyl ligands led to multifunctional materials with excellent photoluminescence and good sorption capacity for carbon dioxide and iodine vapor.

    Original languageEnglish (US)
    Pages (from-to)6408-6415
    Number of pages8
    JournalNew Journal of Chemistry
    Volume42
    Issue number8
    DOIs
    StatePublished - 2018

    ASJC Scopus subject areas

    • Catalysis
    • General Chemistry
    • Materials Chemistry

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