From ruthenium olefin metathesis catalyst to (η5-3- phenylindenyl)hydrido complex via alcoholysis

Simone Manzini; David J. Nelson; Tomáš Lébl; Albert Poater; Luigi Cavallo; Alexandra M. Z. Slawin; Steven P. Nolan

doi:10.1039/c3cc49481k

From ruthenium olefin metathesis catalyst to (η5-3- phenylindenyl)hydrido complex via alcoholysis

Simone Manzini, David J. Nelson, Tomáš Lébl, Albert Poater, Luigi Cavallo, Alexandra M. Z. Slawin, Steven P. Nolan

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

The synthesis and characterisation of [Ru(H)(η5-3- phenylindenyl)(iBu-Phoban)2] 4 is reported ( iBu-Phoban = 9-isobutyl-9-phosphabicyclo-[3.3.1]-nonane). 4 is obtained via alcoholysis of metathesis pre-catalyst M11, in a process that was previously thought to be limited to analogous complex [RuCl 2(PPh3)2(3-phenylindenylidene)] (M 10). This journal is © The Royal Society of Chemistry.

Original language	English (US)
Pages (from-to)	2205
Journal	Chemical Communications
Volume	50
Issue number	17
DOIs	https://doi.org/10.1039/c3cc49481k
State	Published - 2014

ASJC Scopus subject areas

Materials Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Ceramics and Composites
General Chemistry
Catalysis
Electronic, Optical and Magnetic Materials

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10.1039/c3cc49481k

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@article{0008bf0799334d288d1025b1e3f1a72c,

title = "From ruthenium olefin metathesis catalyst to (η5-3- phenylindenyl)hydrido complex via alcoholysis",

abstract = "The synthesis and characterisation of [Ru(H)(η5-3- phenylindenyl)(iBu-Phoban)2] 4 is reported ( iBu-Phoban = 9-isobutyl-9-phosphabicyclo-[3.3.1]-nonane). 4 is obtained via alcoholysis of metathesis pre-catalyst M11, in a process that was previously thought to be limited to analogous complex [RuCl 2(PPh3)2(3-phenylindenylidene)] (M 10). This journal is {\textcopyright} The Royal Society of Chemistry.",

author = "Simone Manzini and Nelson, {David J.} and Tom{\'a}{\v s} L{\'e}bl and Albert Poater and Luigi Cavallo and Slawin, {Alexandra M. Z.} and Nolan, {Steven P.}",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Research leading to these results has received funding from the European Community's Seventh Framework Programme (FP7/ 2007-2013) under grant agreement no. CP-FP 211468-2 EUMET. SPN thanks the ERC for Advanced Investigator Award 'FUNCAT'. SPN is a Royal Society Wolfson Research Merit Award holder. LC thanks BSC (QCM-2010-2-0020), and the HPC team of Enea for using the ENEA-GRID and the HPC facilities CRESCO in Portici (Italy) for access to remarkable computational resources. AP thanks the Spanish MICINN for a Ramon y Cajal contract (RYC-2009-04170) and Generalitat de Catalunya for a BE-DGR fellowship. We thank Umicore for gifts of materials and ligands.",

year = "2014",

doi = "10.1039/c3cc49481k",

language = "English (US)",

volume = "50",

pages = "2205",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "ROYAL SOC CHEMISTRY",

number = "17",

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TY - JOUR

T1 - From ruthenium olefin metathesis catalyst to (η5-3- phenylindenyl)hydrido complex via alcoholysis

AU - Manzini, Simone

AU - Nelson, David J.

AU - Lébl, Tomáš

AU - Poater, Albert

AU - Cavallo, Luigi

AU - Slawin, Alexandra M. Z.

AU - Nolan, Steven P.

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Research leading to these results has received funding from the European Community's Seventh Framework Programme (FP7/ 2007-2013) under grant agreement no. CP-FP 211468-2 EUMET. SPN thanks the ERC for Advanced Investigator Award 'FUNCAT'. SPN is a Royal Society Wolfson Research Merit Award holder. LC thanks BSC (QCM-2010-2-0020), and the HPC team of Enea for using the ENEA-GRID and the HPC facilities CRESCO in Portici (Italy) for access to remarkable computational resources. AP thanks the Spanish MICINN for a Ramon y Cajal contract (RYC-2009-04170) and Generalitat de Catalunya for a BE-DGR fellowship. We thank Umicore for gifts of materials and ligands.

PY - 2014

Y1 - 2014

N2 - The synthesis and characterisation of [Ru(H)(η5-3- phenylindenyl)(iBu-Phoban)2] 4 is reported ( iBu-Phoban = 9-isobutyl-9-phosphabicyclo-[3.3.1]-nonane). 4 is obtained via alcoholysis of metathesis pre-catalyst M11, in a process that was previously thought to be limited to analogous complex [RuCl 2(PPh3)2(3-phenylindenylidene)] (M 10). This journal is © The Royal Society of Chemistry.

AB - The synthesis and characterisation of [Ru(H)(η5-3- phenylindenyl)(iBu-Phoban)2] 4 is reported ( iBu-Phoban = 9-isobutyl-9-phosphabicyclo-[3.3.1]-nonane). 4 is obtained via alcoholysis of metathesis pre-catalyst M11, in a process that was previously thought to be limited to analogous complex [RuCl 2(PPh3)2(3-phenylindenylidene)] (M 10). This journal is © The Royal Society of Chemistry.

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U2 - 10.1039/c3cc49481k

DO - 10.1039/c3cc49481k

M3 - Article

SN - 1359-7345

VL - 50

SP - 2205

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

From ruthenium olefin metathesis catalyst to (η5-3- phenylindenyl)hydrido complex via alcoholysis

Abstract

ASJC Scopus subject areas

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CCDC 976892: Experimental Crystal Structure Determination : Hydrido-(eta^5^-3-phenylindenyl)-bis(9-isobutyl-9-phosphabicyclo[3.3.1]nonane)-ruthenium

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From ruthenium olefin metathesis catalyst to (η5-3- phenylindenyl)hydrido complex via alcoholysis

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 976892: Experimental Crystal Structure Determination : Hydrido-(eta^5^-3-phenylindenyl)-bis(9-isobutyl-9-phosphabicyclo[3.3.1]nonane)-ruthenium

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