From synthesis to chemical reactivity of supported d0 complexes. Part 2. Reactivity of silica-anchored alkylzirconium complexes. An attempt toward functionaltzation of alkanes

Françoise Quignard; Agnès Choplin; Jean Marie Basset

doi:10.1039/DT9940002411

From synthesis to chemical reactivity of supported d⁰ complexes. Part 2. Reactivity of silica-anchored alkylzirconium complexes. An attempt toward functionaltzation of alkanes

Françoise Quignard^*, Agnès Choplin, Jean Marie Basset

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Silica-anchored alkyl zirconium complexes [Zr]_s-R (R = cyclooctyl, Pr or Me) have been generated by reaction of [Zr]_s-H complexes with the relevant alkanes. Their stoichiometric reactivity towards molecules such as carbon monoxide and olefins was studied in order to estimate the potential of such systems to activate and functionalize alkanes catalytically.

Original language	English (US)
Pages (from-to)	2411-2414
Number of pages	4
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	16
DOIs	https://doi.org/10.1039/DT9940002411
State	Published - 1994
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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10.1039/DT9940002411

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title = "From synthesis to chemical reactivity of supported d0 complexes. Part 2. Reactivity of silica-anchored alkylzirconium complexes. An attempt toward functionaltzation of alkanes",

abstract = "Silica-anchored alkyl zirconium complexes [Zr]s-R (R = cyclooctyl, Pr or Me) have been generated by reaction of [Zr]s-H complexes with the relevant alkanes. Their stoichiometric reactivity towards molecules such as carbon monoxide and olefins was studied in order to estimate the potential of such systems to activate and functionalize alkanes catalytically.",

author = "Fran{\c c}oise Quignard and Agn{\`e}s Choplin and Basset, {Jean Marie}",

year = "1994",

doi = "10.1039/DT9940002411",

language = "English (US)",

pages = "2411--2414",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1472-7773",

publisher = "Royal Society of Chemistry",

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}

From synthesis to chemical reactivity of supported d⁰ complexes. Part 2. Reactivity of silica-anchored alkylzirconium complexes. An attempt toward functionaltzation of alkanes. / Quignard, Françoise; Choplin, Agnès; Basset, Jean Marie.
In: Journal of the Chemical Society, Dalton Transactions, No. 16, 1994, p. 2411-2414.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - From synthesis to chemical reactivity of supported d0 complexes. Part 2. Reactivity of silica-anchored alkylzirconium complexes. An attempt toward functionaltzation of alkanes

AU - Quignard, Françoise

AU - Choplin, Agnès

AU - Basset, Jean Marie

PY - 1994

Y1 - 1994

N2 - Silica-anchored alkyl zirconium complexes [Zr]s-R (R = cyclooctyl, Pr or Me) have been generated by reaction of [Zr]s-H complexes with the relevant alkanes. Their stoichiometric reactivity towards molecules such as carbon monoxide and olefins was studied in order to estimate the potential of such systems to activate and functionalize alkanes catalytically.

AB - Silica-anchored alkyl zirconium complexes [Zr]s-R (R = cyclooctyl, Pr or Me) have been generated by reaction of [Zr]s-H complexes with the relevant alkanes. Their stoichiometric reactivity towards molecules such as carbon monoxide and olefins was studied in order to estimate the potential of such systems to activate and functionalize alkanes catalytically.

UR - http://www.scopus.com/inward/record.url?scp=37049071478&partnerID=8YFLogxK

U2 - 10.1039/DT9940002411

DO - 10.1039/DT9940002411

M3 - Article

AN - SCOPUS:37049071478

SN - 1472-7773

SP - 2411

EP - 2414

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 16

ER -

From synthesis to chemical reactivity of supported d⁰ complexes. Part 2. Reactivity of silica-anchored alkylzirconium complexes. An attempt toward functionaltzation of alkanes

Abstract

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