Fullerene/cobalt porphyrin hybrid nanosheets with ambipolar charge transporting characteristics

Takatsugu Wakahara; Pasquale D'Angelo; Kun'Ichi Miyazawa; Yoshihiro Nemoto; Osamu Ito; Nobutaka Tanigaki; Donal D.C. Bradley; Thomas D. Anthopoulos

doi:10.1021/ja211951v

Fullerene/cobalt porphyrin hybrid nanosheets with ambipolar charge transporting characteristics

Takatsugu Wakahara^*, Pasquale D'Angelo, Kun'Ichi Miyazawa, Yoshihiro Nemoto, Osamu Ito, Nobutaka Tanigaki, Donal D.C. Bradley, Thomas D. Anthopoulos

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

116 Scopus citations

Abstract

A novel supramolecular nanoarchitecture, comprising C ₆₀/Co porphyrin nanosheets, was prepared by a simple liquid-liquid interfacial precipitation method and fully characterized by means of optical microscopy, AFM, STEM, TEM, and XRD. It is established that the highly crystalline C ₆₀/Co porphyrin nanosheets have a simple (1:1) stoichiometry, and when incorporated in bottom-gate, bottom-contact field-effect transistors (FETs), they show ambipolar charge transport characteristics.

Original language	English (US)
Pages (from-to)	7204-7206
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	134
Issue number	17
DOIs	https://doi.org/10.1021/ja211951v
State	Published - May 2 2012
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
Biochemistry
Catalysis
Colloid and Surface Chemistry

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title = "Fullerene/cobalt porphyrin hybrid nanosheets with ambipolar charge transporting characteristics",

abstract = "A novel supramolecular nanoarchitecture, comprising C 60/Co porphyrin nanosheets, was prepared by a simple liquid-liquid interfacial precipitation method and fully characterized by means of optical microscopy, AFM, STEM, TEM, and XRD. It is established that the highly crystalline C 60/Co porphyrin nanosheets have a simple (1:1) stoichiometry, and when incorporated in bottom-gate, bottom-contact field-effect transistors (FETs), they show ambipolar charge transport characteristics.",

author = "Takatsugu Wakahara and Pasquale D'Angelo and Kun'Ichi Miyazawa and Yoshihiro Nemoto and Osamu Ito and Nobutaka Tanigaki and Bradley, {Donal D.C.} and Anthopoulos, {Thomas D.}",

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AU - Wakahara, Takatsugu

AU - D'Angelo, Pasquale

AU - Miyazawa, Kun'Ichi

AU - Nemoto, Yoshihiro

AU - Ito, Osamu

AU - Tanigaki, Nobutaka

AU - Bradley, Donal D.C.

AU - Anthopoulos, Thomas D.

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AB - A novel supramolecular nanoarchitecture, comprising C 60/Co porphyrin nanosheets, was prepared by a simple liquid-liquid interfacial precipitation method and fully characterized by means of optical microscopy, AFM, STEM, TEM, and XRD. It is established that the highly crystalline C 60/Co porphyrin nanosheets have a simple (1:1) stoichiometry, and when incorporated in bottom-gate, bottom-contact field-effect transistors (FETs), they show ambipolar charge transport characteristics.

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IS - 17

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Fullerene/cobalt porphyrin hybrid nanosheets with ambipolar charge transporting characteristics

Abstract

ASJC Scopus subject areas

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