Functionalised trimethylsilyl reagents in cluster synthesis: Reactions of Ph2P(S)SSiMe3 with group 11 salts

Maryam Shafaei-Fallah; Christopher E. Anson; Dieter Fenske; Alexander Rothenberger

doi:10.1039/b501360g

Functionalised trimethylsilyl reagents in cluster synthesis: Reactions of Ph₂P(S)SSiMe₃ with group 11 salts

Maryam Shafaei-Fallah, Christopher E. Anson, Dieter Fenske^*, Alexander Rothenberger

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

A series of complexes, ranging from the small cluster l/∞[Ag(Ph ₂PS₂)(dppe)]_∞ [dppe = 1,2-bis(diphenylphosphino)-ethane] to [Cu₄₈S₂₀(O ^tBu)₂(Ph₂PS₂)₂(dppm ^-)₄(dppm)₄] [dppm = 1,2-bis(diphenylphosphino) methane] (the largest Cu cluster containing phosphinodithioato ligands), has been synthesised. The structural evidence presented here indicates that in these reactions initially small cyclic aggregates or one-dimensional coordination polymers are formed. The growth of these intermediates to larger aggregates can take up to several months and could proceed via cationic intermediates.

Original language	English (US)
Pages (from-to)	2300-2304
Number of pages	5
Journal	Dalton transactions
Issue number	13
DOIs	https://doi.org/10.1039/b501360g
State	Published - Jul 7 2005
Externally published	Yes

ASJC Scopus subject areas

Inorganic Chemistry

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title = "Functionalised trimethylsilyl reagents in cluster synthesis: Reactions of Ph2P(S)SSiMe3 with group 11 salts",

abstract = "A series of complexes, ranging from the small cluster l/∞[Ag(Ph 2PS2)(dppe)]∞ [dppe = 1,2-bis(diphenylphosphino)-ethane] to [Cu48S20(O tBu)2(Ph2PS2)2(dppm -)4(dppm)4] [dppm = 1,2-bis(diphenylphosphino) methane] (the largest Cu cluster containing phosphinodithioato ligands), has been synthesised. The structural evidence presented here indicates that in these reactions initially small cyclic aggregates or one-dimensional coordination polymers are formed. The growth of these intermediates to larger aggregates can take up to several months and could proceed via cationic intermediates.",

author = "Maryam Shafaei-Fallah and Anson, {Christopher E.} and Dieter Fenske and Alexander Rothenberger",

year = "2005",

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T1 - Functionalised trimethylsilyl reagents in cluster synthesis

T2 - Reactions of Ph2P(S)SSiMe3 with group 11 salts

AU - Shafaei-Fallah, Maryam

AU - Anson, Christopher E.

AU - Fenske, Dieter

AU - Rothenberger, Alexander

PY - 2005/7/7

Y1 - 2005/7/7

N2 - A series of complexes, ranging from the small cluster l/∞[Ag(Ph 2PS2)(dppe)]∞ [dppe = 1,2-bis(diphenylphosphino)-ethane] to [Cu48S20(O tBu)2(Ph2PS2)2(dppm -)4(dppm)4] [dppm = 1,2-bis(diphenylphosphino) methane] (the largest Cu cluster containing phosphinodithioato ligands), has been synthesised. The structural evidence presented here indicates that in these reactions initially small cyclic aggregates or one-dimensional coordination polymers are formed. The growth of these intermediates to larger aggregates can take up to several months and could proceed via cationic intermediates.

AB - A series of complexes, ranging from the small cluster l/∞[Ag(Ph 2PS2)(dppe)]∞ [dppe = 1,2-bis(diphenylphosphino)-ethane] to [Cu48S20(O tBu)2(Ph2PS2)2(dppm -)4(dppm)4] [dppm = 1,2-bis(diphenylphosphino) methane] (the largest Cu cluster containing phosphinodithioato ligands), has been synthesised. The structural evidence presented here indicates that in these reactions initially small cyclic aggregates or one-dimensional coordination polymers are formed. The growth of these intermediates to larger aggregates can take up to several months and could proceed via cationic intermediates.

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SN - 1477-9226

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JF - Dalton transactions

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ER -

Functionalised trimethylsilyl reagents in cluster synthesis: Reactions of Ph₂P(S)SSiMe₃ with group 11 salts

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