Gas permeation properties of poly(alkyl acetylenes)

A. Morisato; Z. He; I. Pinnau

Gas permeation properties of poly(alkyl acetylenes)

A. Morisato^*, Z. He, I. Pinnau

^*Corresponding author for this work

Research output: Contribution to journal › Comment/debate › peer-review

Abstract

The pure- and mixed-gas permeation properties of poly(alkyl acetylenes) were compared with those of poly(4-methyl-2-pentyne) and other highly permeable, branched polyacetylenes. Gas permeabilities of a systematic series of disubstituted poly(alkyl acetylenes) with carbon numbers of 6, poly(2-hexyne), to 11, poly(2-undecyne), were determined for N₂, O₂, CH₄, H₂, CO₂, C₂H₆, C₃H₈, and n-C₄H₁₀. Unlike low-free-volume glassy polymers, these poly(alkyl acetylenes) had higher permeabilities to C₂₊ hydrocarbons than to methane. However, poly(alkyl acetylenes) have lower permeabilities than branched, disubstituted polyacetylenes, such as poly(4-methyl-2-pentyne). Polyacetylene-based polymers have been studied extensively in the last decade for the separation of gases and vapors.

Original language	English (US)
Pages (from-to)	MACR-12
Journal	ACS National Meeting Book of Abstracts
Volume	PART 2
State	Published - 1999
Externally published	Yes
Event	Proceedings of the 1999 218th ACS National Meeting - New Oeleans, LA, United States Duration: Aug 22 1999 → Aug 26 1999

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

Cite this

@article{5ffb03acaaaf4961ba6e9b25a9bc6e3d,

title = "Gas permeation properties of poly(alkyl acetylenes)",

abstract = "The pure- and mixed-gas permeation properties of poly(alkyl acetylenes) were compared with those of poly(4-methyl-2-pentyne) and other highly permeable, branched polyacetylenes. Gas permeabilities of a systematic series of disubstituted poly(alkyl acetylenes) with carbon numbers of 6, poly(2-hexyne), to 11, poly(2-undecyne), were determined for N2, O2, CH4, H2, CO2, C2H6, C3H8, and n-C4H10. Unlike low-free-volume glassy polymers, these poly(alkyl acetylenes) had higher permeabilities to C2+ hydrocarbons than to methane. However, poly(alkyl acetylenes) have lower permeabilities than branched, disubstituted polyacetylenes, such as poly(4-methyl-2-pentyne). Polyacetylene-based polymers have been studied extensively in the last decade for the separation of gases and vapors.",

author = "A. Morisato and Z. He and I. Pinnau",

year = "1999",

language = "English (US)",

volume = "PART 2",

pages = "MACR--12",

journal = "ACS National Meeting Book of Abstracts",

issn = "0065-7727",

publisher = "American Chemical Society",

note = "Proceedings of the 1999 218th ACS National Meeting ; Conference date: 22-08-1999 Through 26-08-1999",

}

TY - JOUR

T1 - Gas permeation properties of poly(alkyl acetylenes)

AU - Morisato, A.

AU - He, Z.

AU - Pinnau, I.

PY - 1999

Y1 - 1999

N2 - The pure- and mixed-gas permeation properties of poly(alkyl acetylenes) were compared with those of poly(4-methyl-2-pentyne) and other highly permeable, branched polyacetylenes. Gas permeabilities of a systematic series of disubstituted poly(alkyl acetylenes) with carbon numbers of 6, poly(2-hexyne), to 11, poly(2-undecyne), were determined for N2, O2, CH4, H2, CO2, C2H6, C3H8, and n-C4H10. Unlike low-free-volume glassy polymers, these poly(alkyl acetylenes) had higher permeabilities to C2+ hydrocarbons than to methane. However, poly(alkyl acetylenes) have lower permeabilities than branched, disubstituted polyacetylenes, such as poly(4-methyl-2-pentyne). Polyacetylene-based polymers have been studied extensively in the last decade for the separation of gases and vapors.

AB - The pure- and mixed-gas permeation properties of poly(alkyl acetylenes) were compared with those of poly(4-methyl-2-pentyne) and other highly permeable, branched polyacetylenes. Gas permeabilities of a systematic series of disubstituted poly(alkyl acetylenes) with carbon numbers of 6, poly(2-hexyne), to 11, poly(2-undecyne), were determined for N2, O2, CH4, H2, CO2, C2H6, C3H8, and n-C4H10. Unlike low-free-volume glassy polymers, these poly(alkyl acetylenes) had higher permeabilities to C2+ hydrocarbons than to methane. However, poly(alkyl acetylenes) have lower permeabilities than branched, disubstituted polyacetylenes, such as poly(4-methyl-2-pentyne). Polyacetylene-based polymers have been studied extensively in the last decade for the separation of gases and vapors.

UR - http://www.scopus.com/inward/record.url?scp=17144462584&partnerID=8YFLogxK

M3 - Comment/debate

AN - SCOPUS:17144462584

SN - 0065-7727

VL - PART 2

SP - MACR-12

JO - ACS National Meeting Book of Abstracts

JF - ACS National Meeting Book of Abstracts

T2 - Proceedings of the 1999 218th ACS National Meeting

Y2 - 22 August 1999 through 26 August 1999

ER -

Gas permeation properties of poly(alkyl acetylenes)

Abstract

ASJC Scopus subject areas

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