Green to highly transmissive switching multicolored electrochromes: Ferrocene pendant group effect on electrochromic properties

Serife Özdemir; Abidin Balan; Derya Baran; Özdemir Doan; Levent Toppare

doi:10.1016/j.reactfunctpolym.2010.11.024

Green to highly transmissive switching multicolored electrochromes: Ferrocene pendant group effect on electrochromic properties

Serife Özdemir, Abidin Balan, Derya Baran, Özdemir Doan, Levent Toppare^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

Two new quinoxaline and ethylenedioxythiophene (EDOT) based polymers; poly(5,8-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-2-(phenyll) -3-ferrocenylquinoxaline) (P1) and poly(5,8-bis(2,3-dihydrothieno[3,4-b][1,4] dioxin-5-yl)-2,3-di(naphthalen-2-yl) quinoxaline) (P2) were synthesized and characterized in terms of their electrochemical and spectroelectrochemical properties. The polymers were both p and n-type dopable. The polymers can be switched between green and transparent states during p-doping/dedoping. They were compared with their previously reported analogues in order to investigate ferrocene pendant group effect on electrochromic characteristics.

Original language	English (US)
Pages (from-to)	168-174
Number of pages	7
Journal	Reactive and Functional Polymers
Volume	71
Issue number	2
DOIs	https://doi.org/10.1016/j.reactfunctpolym.2010.11.024
State	Published - Feb 2011
Externally published	Yes

Keywords

Donor-acceptor
Electrochromism
Ferrocene
Substitution effect

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Materials Chemistry
Polymers and Plastics
Biochemistry
Environmental Chemistry

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10.1016/j.reactfunctpolym.2010.11.024

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title = "Green to highly transmissive switching multicolored electrochromes: Ferrocene pendant group effect on electrochromic properties",

abstract = "Two new quinoxaline and ethylenedioxythiophene (EDOT) based polymers; poly(5,8-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-2-(phenyll) -3-ferrocenylquinoxaline) (P1) and poly(5,8-bis(2,3-dihydrothieno[3,4-b][1,4] dioxin-5-yl)-2,3-di(naphthalen-2-yl) quinoxaline) (P2) were synthesized and characterized in terms of their electrochemical and spectroelectrochemical properties. The polymers were both p and n-type dopable. The polymers can be switched between green and transparent states during p-doping/dedoping. They were compared with their previously reported analogues in order to investigate ferrocene pendant group effect on electrochromic characteristics.",

keywords = "Donor-acceptor, Electrochromism, Ferrocene, Substitution effect",

author = "Serife {\"O}zdemir and Abidin Balan and Derya Baran and {\"O}zdemir Doan and Levent Toppare",

year = "2011",

month = feb,

doi = "10.1016/j.reactfunctpolym.2010.11.024",

language = "English (US)",

volume = "71",

pages = "168--174",

journal = "Reactive and Functional Polymers",

issn = "1381-5148",

publisher = "Elsevier",

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TY - JOUR

T1 - Green to highly transmissive switching multicolored electrochromes

T2 - Ferrocene pendant group effect on electrochromic properties

AU - Özdemir, Serife

AU - Balan, Abidin

AU - Baran, Derya

AU - Doan, Özdemir

AU - Toppare, Levent

PY - 2011/2

Y1 - 2011/2

N2 - Two new quinoxaline and ethylenedioxythiophene (EDOT) based polymers; poly(5,8-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-2-(phenyll) -3-ferrocenylquinoxaline) (P1) and poly(5,8-bis(2,3-dihydrothieno[3,4-b][1,4] dioxin-5-yl)-2,3-di(naphthalen-2-yl) quinoxaline) (P2) were synthesized and characterized in terms of their electrochemical and spectroelectrochemical properties. The polymers were both p and n-type dopable. The polymers can be switched between green and transparent states during p-doping/dedoping. They were compared with their previously reported analogues in order to investigate ferrocene pendant group effect on electrochromic characteristics.

AB - Two new quinoxaline and ethylenedioxythiophene (EDOT) based polymers; poly(5,8-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-2-(phenyll) -3-ferrocenylquinoxaline) (P1) and poly(5,8-bis(2,3-dihydrothieno[3,4-b][1,4] dioxin-5-yl)-2,3-di(naphthalen-2-yl) quinoxaline) (P2) were synthesized and characterized in terms of their electrochemical and spectroelectrochemical properties. The polymers were both p and n-type dopable. The polymers can be switched between green and transparent states during p-doping/dedoping. They were compared with their previously reported analogues in order to investigate ferrocene pendant group effect on electrochromic characteristics.

KW - Donor-acceptor

KW - Electrochromism

KW - Ferrocene

KW - Substitution effect

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U2 - 10.1016/j.reactfunctpolym.2010.11.024

DO - 10.1016/j.reactfunctpolym.2010.11.024

M3 - Article

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SN - 1381-5148

VL - 71

SP - 168

EP - 174

JO - Reactive and Functional Polymers

JF - Reactive and Functional Polymers

IS - 2

ER -

Green to highly transmissive switching multicolored electrochromes: Ferrocene pendant group effect on electrochromic properties

Abstract

Keywords

ASJC Scopus subject areas

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