Harnessing the potential of N-heterocyclic carbenes for the rejuvenation of group-transfer polymerization of (meth)acrylics

Jean Raynaud; Andres Ciolino; Antoine Baceiredo; Mathias Destarac; Fabien Bonnette; Tsuyoshi Kato; Yves Gnanou; Daniel Taton

doi:10.1002/anie.200800490

Harnessing the potential of N-heterocyclic carbenes for the rejuvenation of group-transfer polymerization of (meth)acrylics

Jean Raynaud^*, Andres Ciolino, Antoine Baceiredo, Mathias Destarac, Fabien Bonnette, Tsuyoshi Kato, Yves Gnanou, Daniel Taton

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

119 Scopus citations

Abstract

(Chemical Equation Presented) Neutral but versatile: N-heterocyclic carbenes are very efficient catalysts for the group-transfer polymerization of acrylates and methacrylates in both polar and apolar media. These organocatalysts were also used to design all-(meth)acrylic di-and triblock copolymers.

Original language	English (US)
Pages (from-to)	5390-5393
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	29
DOIs	https://doi.org/10.1002/anie.200800490
State	Published - Jul 7 2008
Externally published	Yes

Keywords

Block copolymers
Carbenes
Organocatalysis
Polymerization

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.200800490

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abstract = "(Chemical Equation Presented) Neutral but versatile: N-heterocyclic carbenes are very efficient catalysts for the group-transfer polymerization of acrylates and methacrylates in both polar and apolar media. These organocatalysts were also used to design all-(meth)acrylic di-and triblock copolymers.",

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AU - Destarac, Mathias

AU - Bonnette, Fabien

AU - Kato, Tsuyoshi

AU - Gnanou, Yves

AU - Taton, Daniel

PY - 2008/7/7

Y1 - 2008/7/7

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AB - (Chemical Equation Presented) Neutral but versatile: N-heterocyclic carbenes are very efficient catalysts for the group-transfer polymerization of acrylates and methacrylates in both polar and apolar media. These organocatalysts were also used to design all-(meth)acrylic di-and triblock copolymers.

KW - Block copolymers

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KW - Organocatalysis

KW - Polymerization

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Harnessing the potential of N-heterocyclic carbenes for the rejuvenation of group-transfer polymerization of (meth)acrylics

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

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