Heterometallic MOFs constructed from thiophene and furandicarboxylate ligands for heavy metal luminescence sensing

Aleksandr A. Sapianik; Marina O. Barsukova; Konstantin A. Kovalenko; Denis G. Samsonenko; Vladimir P. Fedin

doi:10.1039/d0dt04047a

Heterometallic MOFs constructed from thiophene and furandicarboxylate ligands for heavy metal luminescence sensing

Aleksandr A. Sapianik^*, Marina O. Barsukova, Konstantin A. Kovalenko, Denis G. Samsonenko, Vladimir P. Fedin

^*Corresponding author for this work

Advanced Membranes and Porous Materials Center

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Rational design of a series of new heterometallic MOFs was carried out by the judicious choice of the corresponding synthesis conditions and ligand geometry. Three heterometallic MOFs (H₂NMe₂)[LiZn(dmf)(tdc)₂]·DMF·H₂O (1), [{LiZn}₂Li₂Zn₂(dmf)₆(tdc)₆]·6DMF·H₂O (2) and [Li₂Zn₂(dmf)₂(fdc)₃]·2DMF·2H₂O (3) were obtained on the basis of the pre-synthesized pivalate complex [Li₂Zn₂(py)₂(piv)₆]. The angle between carboxylic groups greatly affects the possibility of retaining the initial tetranuclear node in the structure of the obtained MOFs. Compound3demonstrates permanent porosity with a calculated BET surface area value of 287 m²g⁻¹. Compounds2and3are capable of heavy metal sorption from their nitrate solution, and a significant flare-up of the luminescence of the obtained inclusion compounds is observed, where the quantum yield of luminescence increases by an order of magnitude in the case of cadmium inclusion.

Original language	English (US)
Pages (from-to)	2807-2814
Number of pages	8
Journal	Dalton transactions
Volume	50
Issue number	8
DOIs	https://doi.org/10.1039/d0dt04047a
State	Published - Feb 28 2021

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Inorganic Chemistry

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@article{5b98f732ad9b445fb2451cf22de114a1,

title = "Heterometallic MOFs constructed from thiophene and furandicarboxylate ligands for heavy metal luminescence sensing",

abstract = "Rational design of a series of new heterometallic MOFs was carried out by the judicious choice of the corresponding synthesis conditions and ligand geometry. Three heterometallic MOFs (H2NMe2)[LiZn(dmf)(tdc)2]·DMF·H2O (1), [{LiZn}2Li2Zn2(dmf)6(tdc)6]·6DMF·H2O (2) and [Li2Zn2(dmf)2(fdc)3]·2DMF·2H2O (3) were obtained on the basis of the pre-synthesized pivalate complex [Li2Zn2(py)2(piv)6]. The angle between carboxylic groups greatly affects the possibility of retaining the initial tetranuclear node in the structure of the obtained MOFs. Compound3demonstrates permanent porosity with a calculated BET surface area value of 287 m2g−1. Compounds2and3are capable of heavy metal sorption from their nitrate solution, and a significant flare-up of the luminescence of the obtained inclusion compounds is observed, where the quantum yield of luminescence increases by an order of magnitude in the case of cadmium inclusion.",

author = "Sapianik, {Aleksandr A.} and Barsukova, {Marina O.} and Kovalenko, {Konstantin A.} and Samsonenko, {Denis G.} and Fedin, {Vladimir P.}",

note = "Funding Information: This study was supported by the Russian Science Foundation grant (no. 19-73-20087). Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",

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AU - Sapianik, Aleksandr A.

AU - Barsukova, Marina O.

AU - Kovalenko, Konstantin A.

AU - Samsonenko, Denis G.

AU - Fedin, Vladimir P.

PY - 2021/2/28

Y1 - 2021/2/28

N2 - Rational design of a series of new heterometallic MOFs was carried out by the judicious choice of the corresponding synthesis conditions and ligand geometry. Three heterometallic MOFs (H2NMe2)[LiZn(dmf)(tdc)2]·DMF·H2O (1), [{LiZn}2Li2Zn2(dmf)6(tdc)6]·6DMF·H2O (2) and [Li2Zn2(dmf)2(fdc)3]·2DMF·2H2O (3) were obtained on the basis of the pre-synthesized pivalate complex [Li2Zn2(py)2(piv)6]. The angle between carboxylic groups greatly affects the possibility of retaining the initial tetranuclear node in the structure of the obtained MOFs. Compound3demonstrates permanent porosity with a calculated BET surface area value of 287 m2g−1. Compounds2and3are capable of heavy metal sorption from their nitrate solution, and a significant flare-up of the luminescence of the obtained inclusion compounds is observed, where the quantum yield of luminescence increases by an order of magnitude in the case of cadmium inclusion.

AB - Rational design of a series of new heterometallic MOFs was carried out by the judicious choice of the corresponding synthesis conditions and ligand geometry. Three heterometallic MOFs (H2NMe2)[LiZn(dmf)(tdc)2]·DMF·H2O (1), [{LiZn}2Li2Zn2(dmf)6(tdc)6]·6DMF·H2O (2) and [Li2Zn2(dmf)2(fdc)3]·2DMF·2H2O (3) were obtained on the basis of the pre-synthesized pivalate complex [Li2Zn2(py)2(piv)6]. The angle between carboxylic groups greatly affects the possibility of retaining the initial tetranuclear node in the structure of the obtained MOFs. Compound3demonstrates permanent porosity with a calculated BET surface area value of 287 m2g−1. Compounds2and3are capable of heavy metal sorption from their nitrate solution, and a significant flare-up of the luminescence of the obtained inclusion compounds is observed, where the quantum yield of luminescence increases by an order of magnitude in the case of cadmium inclusion.

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C2 - 33533376

AN - SCOPUS:85101977395

SN - 1477-9226

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JO - Dalton transactions

JF - Dalton transactions

IS - 8

ER -

Heterometallic MOFs constructed from thiophene and furandicarboxylate ligands for heavy metal luminescence sensing

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