Hexaarm star-shaped polystyrenes by core-first method

Eric Cloutet; Jean Luc Fillaut; Yves Gnanou; Didier Astruc

doi:10.1039/C39940002433

Hexaarm star-shaped polystyrenes by core-first method

Eric Cloutet^*, Jean Luc Fillaut, Yves Gnanou, Didier Astruc

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

The hexafunctional initiator C₆[(CH₂) ₂p-C₆H₄CH(Cl)Me]₆ is synthesized by Fe(η-C₅H₅)⁺ induced hexabenzylation of C₆Me₆ followed by regiospecific acetylation, NaBH ₄ reduction and chlorination, and allows the living cationic polymerization of styrene which yields hexaarm star-shaped polymers.

Original language	English (US)
Pages (from-to)	2433-2434
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	21
DOIs	https://doi.org/10.1039/C39940002433
State	Published - 1994
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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@article{a4314d9638a54812a626f2229d6e7669,

title = "Hexaarm star-shaped polystyrenes by core-first method",

abstract = "The hexafunctional initiator C6[(CH2) 2p-C6H4CH(Cl)Me]6 is synthesized by Fe(η-C5H5)+ induced hexabenzylation of C6Me6 followed by regiospecific acetylation, NaBH 4 reduction and chlorination, and allows the living cationic polymerization of styrene which yields hexaarm star-shaped polymers.",

author = "Eric Cloutet and Fillaut, {Jean Luc} and Yves Gnanou and Didier Astruc",

year = "1994",

doi = "10.1039/C39940002433",

language = "English (US)",

pages = "2433--2434",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "21",

}

TY - JOUR

T1 - Hexaarm star-shaped polystyrenes by core-first method

AU - Cloutet, Eric

AU - Fillaut, Jean Luc

AU - Gnanou, Yves

AU - Astruc, Didier

PY - 1994

Y1 - 1994

N2 - The hexafunctional initiator C6[(CH2) 2p-C6H4CH(Cl)Me]6 is synthesized by Fe(η-C5H5)+ induced hexabenzylation of C6Me6 followed by regiospecific acetylation, NaBH 4 reduction and chlorination, and allows the living cationic polymerization of styrene which yields hexaarm star-shaped polymers.

AB - The hexafunctional initiator C6[(CH2) 2p-C6H4CH(Cl)Me]6 is synthesized by Fe(η-C5H5)+ induced hexabenzylation of C6Me6 followed by regiospecific acetylation, NaBH 4 reduction and chlorination, and allows the living cationic polymerization of styrene which yields hexaarm star-shaped polymers.

UR - http://www.scopus.com/inward/record.url?scp=37049082130&partnerID=8YFLogxK

U2 - 10.1039/C39940002433

DO - 10.1039/C39940002433

M3 - Article

AN - SCOPUS:37049082130

SN - 0022-4936

SP - 2433

EP - 2434

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 21

ER -

Hexaarm star-shaped polystyrenes by core-first method

Abstract

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