High performance of proton-conducting solid oxide fuel cell with a layered PrBaCo2O5+δ cathode

Ling Zhao; Beibei He; Bin Lin; Hanping Ding; Songlin Wang; Yihan Ling; Ranran Peng; Guangyao Meng; Xingqin Liu

doi:10.1016/j.jpowsour.2009.06.010

High performance of proton-conducting solid oxide fuel cell with a layered PrBaCo₂O_5+δ cathode

Ling Zhao, Beibei He, Bin Lin, Hanping Ding, Songlin Wang, Yihan Ling, Ranran Peng, Guangyao Meng, Xingqin Liu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

118 Scopus citations

Abstract

A dense BaZr_0.1Ce_0.7Y_0.2O_3-δ (BZCY) electrolyte is fabricated on a porous anode by in situ drop-coating method which can lead to extremely thin electrolyte membrane (∼10 μm in thickness). The layered perovskite structure oxide PrBaCo₂O_5+δ (PBCO) is synthesized by auto ignition process and initially examined as a cathode for proton-conducting IT-SOFCs. The electrical conductivity of PrBaCo₂O_5+δ (PBCO) reaches the general required value for the electrical conductivity of cathode absolutely. The single cell, consisting of PrBaCo₂O_5+δ (PBCO)/BaZr_0.1Ce_0.7Y_0.2O_3-δ (BZCY)/NiO-BaZr_0.1Ce_0.7Y_0.2O_3-δ (BZCY) structure, is assembled and tested from 600 to 700 °C with humidified hydrogen (∼3% H₂O) as the fuel and air as the oxidant. An open-circuit potential of 1.01 V and a maximum power density of 545 mW cm^-2 at 700 °C are obtained for the single cell, and a low polarization resistance of the electrodes of 0.15 Ω cm² is achieved at 700 °C.

Original language	English (US)
Pages (from-to)	835-837
Number of pages	3
Journal	Journal of Power Sources
Volume	194
Issue number	2
DOIs	https://doi.org/10.1016/j.jpowsour.2009.06.010
State	Published - Dec 1 2009
Externally published	Yes

Keywords

Cathode
High performance
Proton-conducting solid oxide fuel cell

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
Energy Engineering and Power Technology
Physical and Theoretical Chemistry
Electrical and Electronic Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.jpowsour.2009.06.010

Cite this

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title = "High performance of proton-conducting solid oxide fuel cell with a layered PrBaCo2O5+δ cathode",

abstract = "A dense BaZr0.1Ce0.7Y0.2O3-δ (BZCY) electrolyte is fabricated on a porous anode by in situ drop-coating method which can lead to extremely thin electrolyte membrane (∼10 μm in thickness). The layered perovskite structure oxide PrBaCo2O5+δ (PBCO) is synthesized by auto ignition process and initially examined as a cathode for proton-conducting IT-SOFCs. The electrical conductivity of PrBaCo2O5+δ (PBCO) reaches the general required value for the electrical conductivity of cathode absolutely. The single cell, consisting of PrBaCo2O5+δ (PBCO)/BaZr0.1Ce0.7Y0.2O3-δ (BZCY)/NiO-BaZr0.1Ce0.7Y0.2O3-δ (BZCY) structure, is assembled and tested from 600 to 700 °C with humidified hydrogen (∼3% H2O) as the fuel and air as the oxidant. An open-circuit potential of 1.01 V and a maximum power density of 545 mW cm-2 at 700 °C are obtained for the single cell, and a low polarization resistance of the electrodes of 0.15 Ω cm2 is achieved at 700 °C.",

keywords = "Cathode, High performance, Proton-conducting solid oxide fuel cell",

author = "Ling Zhao and Beibei He and Bin Lin and Hanping Ding and Songlin Wang and Yihan Ling and Ranran Peng and Guangyao Meng and Xingqin Liu",

year = "2009",

month = dec,

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doi = "10.1016/j.jpowsour.2009.06.010",

language = "English (US)",

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T1 - High performance of proton-conducting solid oxide fuel cell with a layered PrBaCo2O5+δ cathode

AU - Zhao, Ling

AU - He, Beibei

AU - Lin, Bin

AU - Ding, Hanping

AU - Wang, Songlin

AU - Ling, Yihan

AU - Peng, Ranran

AU - Meng, Guangyao

AU - Liu, Xingqin

PY - 2009/12/1

Y1 - 2009/12/1

N2 - A dense BaZr0.1Ce0.7Y0.2O3-δ (BZCY) electrolyte is fabricated on a porous anode by in situ drop-coating method which can lead to extremely thin electrolyte membrane (∼10 μm in thickness). The layered perovskite structure oxide PrBaCo2O5+δ (PBCO) is synthesized by auto ignition process and initially examined as a cathode for proton-conducting IT-SOFCs. The electrical conductivity of PrBaCo2O5+δ (PBCO) reaches the general required value for the electrical conductivity of cathode absolutely. The single cell, consisting of PrBaCo2O5+δ (PBCO)/BaZr0.1Ce0.7Y0.2O3-δ (BZCY)/NiO-BaZr0.1Ce0.7Y0.2O3-δ (BZCY) structure, is assembled and tested from 600 to 700 °C with humidified hydrogen (∼3% H2O) as the fuel and air as the oxidant. An open-circuit potential of 1.01 V and a maximum power density of 545 mW cm-2 at 700 °C are obtained for the single cell, and a low polarization resistance of the electrodes of 0.15 Ω cm2 is achieved at 700 °C.

AB - A dense BaZr0.1Ce0.7Y0.2O3-δ (BZCY) electrolyte is fabricated on a porous anode by in situ drop-coating method which can lead to extremely thin electrolyte membrane (∼10 μm in thickness). The layered perovskite structure oxide PrBaCo2O5+δ (PBCO) is synthesized by auto ignition process and initially examined as a cathode for proton-conducting IT-SOFCs. The electrical conductivity of PrBaCo2O5+δ (PBCO) reaches the general required value for the electrical conductivity of cathode absolutely. The single cell, consisting of PrBaCo2O5+δ (PBCO)/BaZr0.1Ce0.7Y0.2O3-δ (BZCY)/NiO-BaZr0.1Ce0.7Y0.2O3-δ (BZCY) structure, is assembled and tested from 600 to 700 °C with humidified hydrogen (∼3% H2O) as the fuel and air as the oxidant. An open-circuit potential of 1.01 V and a maximum power density of 545 mW cm-2 at 700 °C are obtained for the single cell, and a low polarization resistance of the electrodes of 0.15 Ω cm2 is achieved at 700 °C.

KW - Cathode

KW - High performance

KW - Proton-conducting solid oxide fuel cell

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