Hole- and Electron-Vibrational Couplings in Oligoacene Crystals: Intramolecular Contributions

V. Coropceanu; M. Malagoli; D. A. da Silva Filho; N. E. Gruhn; T. G. Bill; J. L. Brédas

doi:10.1103/PhysRevLett.89.275503

Hole- and Electron-Vibrational Couplings in Oligoacene Crystals: Intramolecular Contributions

V. Coropceanu, M. Malagoli, D. A. da Silva Filho, N. E. Gruhn, T. G. Bill, J. L. Brédas

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380 Scopus citations

Abstract

The hole-vibrational coupling is reported for anthracene, tetracene, and pentacene on the basis of a joint experimental and theoretical study of ionization spectra using high-resolution gas-phase photoelectron spectroscopy and first-principles correlated quantum-mechanical calculations. The hole-vibrational coupling is found to be significantly smaller than the electron-vibrational coupling in the case of these oligomers; however, both quantities are predicted to converge to the same value when increasing the chain length.

Original language	English (US)
Journal	Physical Review Letters
Volume	89
Issue number	27
DOIs	https://doi.org/10.1103/PhysRevLett.89.275503
State	Published - 2002
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy

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title = "Hole- and Electron-Vibrational Couplings in Oligoacene Crystals: Intramolecular Contributions",

abstract = "The hole-vibrational coupling is reported for anthracene, tetracene, and pentacene on the basis of a joint experimental and theoretical study of ionization spectra using high-resolution gas-phase photoelectron spectroscopy and first-principles correlated quantum-mechanical calculations. The hole-vibrational coupling is found to be significantly smaller than the electron-vibrational coupling in the case of these oligomers; however, both quantities are predicted to converge to the same value when increasing the chain length.",

author = "V. Coropceanu and M. Malagoli and {da Silva Filho}, {D. A.} and Gruhn, {N. E.} and Bill, {T. G.} and Br{\'e}das, {J. L.}",

year = "2002",

doi = "10.1103/PhysRevLett.89.275503",

language = "English (US)",

volume = "89",

journal = "Physical Review Letters",

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AU - Coropceanu, V.

AU - Malagoli, M.

AU - da Silva Filho, D. A.

AU - Gruhn, N. E.

AU - Bill, T. G.

AU - Brédas, J. L.

PY - 2002

Y1 - 2002

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AB - The hole-vibrational coupling is reported for anthracene, tetracene, and pentacene on the basis of a joint experimental and theoretical study of ionization spectra using high-resolution gas-phase photoelectron spectroscopy and first-principles correlated quantum-mechanical calculations. The hole-vibrational coupling is found to be significantly smaller than the electron-vibrational coupling in the case of these oligomers; however, both quantities are predicted to converge to the same value when increasing the chain length.

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Hole- and Electron-Vibrational Couplings in Oligoacene Crystals: Intramolecular Contributions

Abstract

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