Abstract
Two types of POCOP-nickel(II) pincer complexes were prepared by mixing POCOP pincer ligands and NiX 2 in toluene at reflux. The resulting nickel complexes efficiently catalyze the homocoupling reactions of benzyl halides in the presence of zinc. The coupled products were obtained in excellent to quantitative yields. © 2012 Elsevier Ltd. All rights reserved.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 6152-6157 |
| Number of pages | 6 |
| Journal | Tetrahedron |
| Volume | 68 |
| Issue number | 31 |
| DOIs | |
| State | Published - Aug 2012 |
ASJC Scopus subject areas
- Biochemistry
- Organic Chemistry
- Drug Discovery
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Dive into the research topics of 'Homocoupling of benzyl halides catalyzed by POCOP-nickel pincer complexes'. Together they form a unique fingerprint.Datasets
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CCDC 879686: Experimental Crystal Structure Determination : (3,5-Di-t-butyl-2,6-bis((diphenylphosphino)oxy)phenyl)-iodo-nickel(ii)
Chen, T. (Creator), Yang, L. (Creator), LI, L. (Creator) & Huang, K.-W. (Creator), Cambridge Crystallographic Data Centre, 2012
DOI: 10.5517/ccyjczs, http://hdl.handle.net/10754/624713
Dataset
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CCDC 879684: Experimental Crystal Structure Determination : chloro-(2,6-bis((bis(cyclopentyl)phosphino)oxy)-4-(ethoxycarbonyl)phenyl)-nickel(ii)
Chen, T. (Creator), Yang, L. (Creator), LI, L. (Creator) & Huang, K.-W. (Creator), Cambridge Crystallographic Data Centre, 2012
DOI: 10.5517/ccyjcxq, http://hdl.handle.net/10754/624711
Dataset
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CCDC 879685: Experimental Crystal Structure Determination : Chloro-(3,5-di-t-butyl-2,6-bis((di-t-butylphosphino)oxy)phenyl)-nickel(ii)
Chen, T. (Creator), Yang, L. (Creator), Li, L. (Creator) & Huang, K.-W. (Creator), Cambridge Crystallographic Data Centre, 2012
DOI: 10.5517/ccyjcyr, http://hdl.handle.net/10754/624712
Dataset