TY - JOUR
T1 - Hybrid metal-organic framework nanomaterials with enhanced carbon dioxide and methane adsorption enthalpy by incorporation of carbon nanotubes
AU - Kang, Zixi
AU - Xue, Ming
AU - Zhang, Daliang
AU - Fan, Lili
AU - Pan, Ying
AU - Qiu, Shilun
N1 - KAUST Repository Item: Exported on 2021-11-01
Acknowledged KAUST grant number(s): CRG-1-2012-LAI-009
Acknowledgements: This work was supported by the National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700), NSFC (21261130584, 21201076, 21101072), 111 project (B07016), and Award Project of KAUST (CRG-1-2012-LAI-009).
This publication acknowledges KAUST support, but has no KAUST affiliated authors.
PY - 2015
Y1 - 2015
N2 - Abstract Two hybrid materials composed of metal-organic framework (JUC-32) nanoparticles and carboxyl-modified multi-wall carbon nanotubes (MWCNTs) were synthesised successfully in situ and characterized by TEM, PXRD, and TGA. The gas adsorption properties of these two hybrid materials were compared with the original JUC-32 material and a physical mixture of JUC-32 and MWCNTs. The results indicated that the composite materials absorbed larger amounts of CO2 and CH4 per specific surface area than the original materials, and that the adsorption enthalpies of CO2 and CH4 had significantly increased.
AB - Abstract Two hybrid materials composed of metal-organic framework (JUC-32) nanoparticles and carboxyl-modified multi-wall carbon nanotubes (MWCNTs) were synthesised successfully in situ and characterized by TEM, PXRD, and TGA. The gas adsorption properties of these two hybrid materials were compared with the original JUC-32 material and a physical mixture of JUC-32 and MWCNTs. The results indicated that the composite materials absorbed larger amounts of CO2 and CH4 per specific surface area than the original materials, and that the adsorption enthalpies of CO2 and CH4 had significantly increased.
UR - http://hdl.handle.net/10754/672995
UR - https://linkinghub.elsevier.com/retrieve/pii/S1387700315002282
UR - http://www.scopus.com/inward/record.url?scp=84931260117&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2015.06.007
DO - 10.1016/j.inoche.2015.06.007
M3 - Article
SN - 1879-0259
VL - 58
SP - 79
EP - 83
JO - INORGANIC CHEMISTRY COMMUNICATIONS
JF - INORGANIC CHEMISTRY COMMUNICATIONS
ER -