TY - JOUR
T1 - Hydrodeoxygenation of raw bio-oil towards platform chemicals over FeMoP/zeolite catalysts
AU - Hita, Idoia
AU - Cordero-Lanzac, Tomás
AU - Bonura, Giuseppe
AU - Cannilla, Catia
AU - Arandes, José M.
AU - Frusteri, Francesco
AU - Bilbao, Javier
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: This work was carried out with the support of the Ministry of Economy and Competitiveness of the Spanish Government, some cofounded with ERDF funds (CTQ2015-67425-R), the Basque Government (IT1218-19) and the European Commission (Horizon H2020-MSCA RISE-2018, Contract No. 823745). Dr. Idoia Hita is grateful for her postdoctoral grant awarded by the Department of Education, University and Research of the Basque Government (POS_2015_1_0035). Authors thank Dr. Enrico Catizzone from UniCAL (Cosenza, Italy) for ICP-MS measurements.
PY - 2019/8/9
Y1 - 2019/8/9
N2 - The hydrodeoxygenation of raw bio-oil was investigated in a continuous fixed bed reactor over a series of FeMoP/zeolite catalysts, pursuing a maximized and stable production of phenolics and aromatics. After 5 h of reaction, the catalysts reach a pseudosteady activity state. The FeMoP/HZSM-5 catalyst yields the highest amount of carbon products (53.5 wt%) with the highest selectivity towards aromatics (13.6 wt%, dry basis) and phenolics (12.2 wt%), due to the synergy between the weak acidity of the FeMoP and the mild acidity of the HZSM-5 zeolite, which minimizes dehydration and gasification. The MFI framework allows the sweeping of coke precursors.
AB - The hydrodeoxygenation of raw bio-oil was investigated in a continuous fixed bed reactor over a series of FeMoP/zeolite catalysts, pursuing a maximized and stable production of phenolics and aromatics. After 5 h of reaction, the catalysts reach a pseudosteady activity state. The FeMoP/HZSM-5 catalyst yields the highest amount of carbon products (53.5 wt%) with the highest selectivity towards aromatics (13.6 wt%, dry basis) and phenolics (12.2 wt%), due to the synergy between the weak acidity of the FeMoP and the mild acidity of the HZSM-5 zeolite, which minimizes dehydration and gasification. The MFI framework allows the sweeping of coke precursors.
UR - http://hdl.handle.net/10754/656824
UR - https://linkinghub.elsevier.com/retrieve/pii/S1226086X19304228
UR - http://www.scopus.com/inward/record.url?scp=85071514332&partnerID=8YFLogxK
U2 - 10.1016/j.jiec.2019.08.019
DO - 10.1016/j.jiec.2019.08.019
M3 - Article
SN - 1226-086X
VL - 80
SP - 392
EP - 400
JO - Journal of Industrial and Engineering Chemistry
JF - Journal of Industrial and Engineering Chemistry
ER -