Hydrogen bonding controlled catalysis of a porous organic framework containing benzimidazole moieties

Bing Liu; Teng Ben; Jun Xu; Feng Deng; Shilun Qiu

doi:10.1039/c4nj00053f

Hydrogen bonding controlled catalysis of a porous organic framework containing benzimidazole moieties

Bing Liu, Teng Ben, Jun Xu, Feng Deng, Shilun Qiu

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

A microporous organic framework (JUC-Z12) was synthesized quantitatively from tetra(4-formylphenyl)methane and 3,3′-diaminobenzidine. JUC-Z12 shows high thermal stability (>400 °C), a large surface area (SBET = 750 m2 g-1), a well-defined uniform micropore distribution (1.09 nm) and high Qst for H2 (-8.1 kJ mol-1), CO2 (-29.5 kJ mol-1), and CH 4 (-22.2 kJ mol-1). It also exhibits selective catalytic activities in the Knoevenagel reaction, which is supposed to be controlled by hydrogen bonding between substrates and JUC-Z12. The JUC-Z12 catalyst can be easily isolated from the reaction mixture by simple filtration and reused with high activity. This journal is © the Partner Organisations 2014.

Original language	English (US)
Pages (from-to)	2292
Journal	New Journal of Chemistry
Volume	38
Issue number	6
DOIs	https://doi.org/10.1039/c4nj00053f
State	Published - 2014
Externally published	Yes

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title = "Hydrogen bonding controlled catalysis of a porous organic framework containing benzimidazole moieties",

abstract = "A microporous organic framework (JUC-Z12) was synthesized quantitatively from tetra(4-formylphenyl)methane and 3,3′-diaminobenzidine. JUC-Z12 shows high thermal stability (>400 °C), a large surface area (SBET = 750 m2 g-1), a well-defined uniform micropore distribution (1.09 nm) and high Qst for H2 (-8.1 kJ mol-1), CO2 (-29.5 kJ mol-1), and CH 4 (-22.2 kJ mol-1). It also exhibits selective catalytic activities in the Knoevenagel reaction, which is supposed to be controlled by hydrogen bonding between substrates and JUC-Z12. The JUC-Z12 catalyst can be easily isolated from the reaction mixture by simple filtration and reused with high activity. This journal is {\textcopyright} the Partner Organisations 2014.",

author = "Bing Liu and Teng Ben and Jun Xu and Feng Deng and Shilun Qiu",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): CRG-1-2012-LAI-009 Acknowledgements: This work was supported by National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700, 2011CB808703), NSFC (21261130584, 91022030), {"}111{"} project (B07016), Award Project of KAUST (CRG-1-2012-LAI-009) and Ministry of Education, Science and Technology Development Center Project (20120061130012). This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

year = "2014",

doi = "10.1039/c4nj00053f",

language = "English (US)",

volume = "38",

pages = "2292",

journal = "New Journal of Chemistry",

issn = "1144-0546",

publisher = "Royal Society of Chemistry",

number = "6",

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TY - JOUR

T1 - Hydrogen bonding controlled catalysis of a porous organic framework containing benzimidazole moieties

AU - Liu, Bing

AU - Ben, Teng

AU - Xu, Jun

AU - Deng, Feng

AU - Qiu, Shilun

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): CRG-1-2012-LAI-009 Acknowledgements: This work was supported by National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700, 2011CB808703), NSFC (21261130584, 91022030), "111" project (B07016), Award Project of KAUST (CRG-1-2012-LAI-009) and Ministry of Education, Science and Technology Development Center Project (20120061130012). This publication acknowledges KAUST support, but has no KAUST affiliated authors.

PY - 2014

Y1 - 2014

N2 - A microporous organic framework (JUC-Z12) was synthesized quantitatively from tetra(4-formylphenyl)methane and 3,3′-diaminobenzidine. JUC-Z12 shows high thermal stability (>400 °C), a large surface area (SBET = 750 m2 g-1), a well-defined uniform micropore distribution (1.09 nm) and high Qst for H2 (-8.1 kJ mol-1), CO2 (-29.5 kJ mol-1), and CH 4 (-22.2 kJ mol-1). It also exhibits selective catalytic activities in the Knoevenagel reaction, which is supposed to be controlled by hydrogen bonding between substrates and JUC-Z12. The JUC-Z12 catalyst can be easily isolated from the reaction mixture by simple filtration and reused with high activity. This journal is © the Partner Organisations 2014.

AB - A microporous organic framework (JUC-Z12) was synthesized quantitatively from tetra(4-formylphenyl)methane and 3,3′-diaminobenzidine. JUC-Z12 shows high thermal stability (>400 °C), a large surface area (SBET = 750 m2 g-1), a well-defined uniform micropore distribution (1.09 nm) and high Qst for H2 (-8.1 kJ mol-1), CO2 (-29.5 kJ mol-1), and CH 4 (-22.2 kJ mol-1). It also exhibits selective catalytic activities in the Knoevenagel reaction, which is supposed to be controlled by hydrogen bonding between substrates and JUC-Z12. The JUC-Z12 catalyst can be easily isolated from the reaction mixture by simple filtration and reused with high activity. This journal is © the Partner Organisations 2014.

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U2 - 10.1039/c4nj00053f

DO - 10.1039/c4nj00053f

M3 - Article

SN - 1144-0546

VL - 38

SP - 2292

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 6

ER -

Hydrogen bonding controlled catalysis of a porous organic framework containing benzimidazole moieties

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