Hydrolysis of CpTiCl2(TEMPO) and its application on one-pot syntheses of CpTiCl(OR)2 complexes

Kuo Wei Huang; Robert M. Waymouth

doi:10.1039/b314027j

Hydrolysis of CpTiCl₂(TEMPO) and its application on one-pot syntheses of CpTiCl(OR)₂ complexes

Kuo Wei Huang, Robert M. Waymouth^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The η¹-hydroxylamido half-titanocene complex, CpTi-Cl₂(TEMPO) 1, hydrolyzes extremely efficiently to generate (CpTiClO)₄ and the protonated hydroxylamine. The efficient hydrolysis chemistry provides selective syntheses of CpTi dialkoxide and diaryloxide complexes.

Original language	English (US)
Pages (from-to)	354-356
Number of pages	3
Journal	Dalton transactions
Issue number	3
DOIs	https://doi.org/10.1039/b314027j
State	Published - Feb 7 2004
Externally published	Yes

ASJC Scopus subject areas

Inorganic Chemistry

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10.1039/b314027j

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title = "Hydrolysis of CpTiCl2(TEMPO) and its application on one-pot syntheses of CpTiCl(OR)2 complexes",

abstract = "The η1-hydroxylamido half-titanocene complex, CpTi-Cl2(TEMPO) 1, hydrolyzes extremely efficiently to generate (CpTiClO)4 and the protonated hydroxylamine. The efficient hydrolysis chemistry provides selective syntheses of CpTi dialkoxide and diaryloxide complexes.",

author = "Huang, {Kuo Wei} and Waymouth, {Robert M.}",

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language = "English (US)",

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journal = "Dalton transactions",

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T1 - Hydrolysis of CpTiCl2(TEMPO) and its application on one-pot syntheses of CpTiCl(OR)2 complexes

AU - Huang, Kuo Wei

AU - Waymouth, Robert M.

PY - 2004/2/7

Y1 - 2004/2/7

N2 - The η1-hydroxylamido half-titanocene complex, CpTi-Cl2(TEMPO) 1, hydrolyzes extremely efficiently to generate (CpTiClO)4 and the protonated hydroxylamine. The efficient hydrolysis chemistry provides selective syntheses of CpTi dialkoxide and diaryloxide complexes.

AB - The η1-hydroxylamido half-titanocene complex, CpTi-Cl2(TEMPO) 1, hydrolyzes extremely efficiently to generate (CpTiClO)4 and the protonated hydroxylamine. The efficient hydrolysis chemistry provides selective syntheses of CpTi dialkoxide and diaryloxide complexes.

UR - http://www.scopus.com/inward/record.url?scp=1242310768&partnerID=8YFLogxK

U2 - 10.1039/b314027j

DO - 10.1039/b314027j

M3 - Article

C2 - 15252536

AN - SCOPUS:1242310768

SN - 1477-9226

SP - 354

EP - 356

JO - Dalton transactions

JF - Dalton transactions

IS - 3

ER -

Hydrolysis of CpTiCl₂(TEMPO) and its application on one-pot syntheses of CpTiCl(OR)₂ complexes

Abstract

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