Hydrotrifluoromethylthiolation of α-diazo esters – synthesis of α-SCF3 substituted esters

Quentin Lefebvre, Eleonora Fava, Pavlo Nikolaienko, Magnus Rueping*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

105 Scopus citations

Abstract

A practical protocol for hydrotrifluoromethylthiolation of diazo compounds has been developed. A range of diazo compounds in combination with a nucleophilic SCF3 source provided access to valuable trifluoromethylthiolated compounds. Furthermore, a methodology for the first double trifluoromethylthiolation was developed.

Original languageEnglish (US)
Pages (from-to)6617-6619
Number of pages3
JournalCHEMICAL COMMUNICATIONS
Volume50
Issue number50
DOIs
StatePublished - May 27 2014
Externally publishedYes

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • General Chemistry
  • Ceramics and Composites
  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Catalysis

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