Hysteresis in the gas sorption isotherms of metal-organic cages accompanied by subtle changes in molecular packing

Gavin A. Craig; Patrick Larpent; Hinano Urabe; Alexandre Legrand; Mickaele Bonneau; Shinpei Kusaka; Shuhei Furukawa

doi:10.1039/d0cc00932f

Hysteresis in the gas sorption isotherms of metal-organic cages accompanied by subtle changes in molecular packing

Gavin A. Craig, Patrick Larpent, Hinano Urabe, Alexandre Legrand, Mickaele Bonneau, Shinpei Kusaka, Shuhei Furukawa

Chemistry

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Structural deformation in response to gas sorption is rarely observed for porous molecular solids, when compared to porous framework materials. Here, we describe the effect of chemical modification on the exterior of lantern-type metal-organic cages on the emergence and then disappearance of cooperative gas uptake. The results suggest that supramolecular design of ligands can be used to reveal this behaviour.

Original language	English (US)
Pages (from-to)	3689-3692
Number of pages	4
Journal	CHEMICAL COMMUNICATIONS
Volume	56
Issue number	25
DOIs	https://doi.org/10.1039/d0cc00932f
State	Published - Mar 28 2020

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/d0cc00932f

Cite this

@article{669615f134624963a501adf355faf49c,

title = "Hysteresis in the gas sorption isotherms of metal-organic cages accompanied by subtle changes in molecular packing",

abstract = "Structural deformation in response to gas sorption is rarely observed for porous molecular solids, when compared to porous framework materials. Here, we describe the effect of chemical modification on the exterior of lantern-type metal-organic cages on the emergence and then disappearance of cooperative gas uptake. The results suggest that supramolecular design of ligands can be used to reveal this behaviour.",

author = "Craig, {Gavin A.} and Patrick Larpent and Hinano Urabe and Alexandre Legrand and Mickaele Bonneau and Shinpei Kusaka and Shuhei Furukawa",

note = "Funding Information: This work was supported by JSPS KAKENHI grant number 19H04575 (Coordination Asymmetry) and 19K05495 (Kiban C). The authors thank the iCeMS Analysis Center for access to analytical instruments. Prof. Susumu Kitagawa (Kyoto University) is thanked for helpful discussion of the manuscript. Dr Alan Kennedy (University of Strathclyde) is acknowledged for assistance with crystallography. Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry.",

year = "2020",

month = mar,

day = "28",

doi = "10.1039/d0cc00932f",

language = "English (US)",

volume = "56",

pages = "3689--3692",

journal = "CHEMICAL COMMUNICATIONS",

issn = "1359-7345",

publisher = "ROYAL SOC CHEMISTRY",

number = "25",

}

TY - JOUR

T1 - Hysteresis in the gas sorption isotherms of metal-organic cages accompanied by subtle changes in molecular packing

AU - Craig, Gavin A.

AU - Larpent, Patrick

AU - Urabe, Hinano

AU - Legrand, Alexandre

AU - Bonneau, Mickaele

AU - Kusaka, Shinpei

AU - Furukawa, Shuhei

N1 - Funding Information: This work was supported by JSPS KAKENHI grant number 19H04575 (Coordination Asymmetry) and 19K05495 (Kiban C). The authors thank the iCeMS Analysis Center for access to analytical instruments. Prof. Susumu Kitagawa (Kyoto University) is thanked for helpful discussion of the manuscript. Dr Alan Kennedy (University of Strathclyde) is acknowledged for assistance with crystallography. Publisher Copyright: This journal is © The Royal Society of Chemistry.

PY - 2020/3/28

Y1 - 2020/3/28

N2 - Structural deformation in response to gas sorption is rarely observed for porous molecular solids, when compared to porous framework materials. Here, we describe the effect of chemical modification on the exterior of lantern-type metal-organic cages on the emergence and then disappearance of cooperative gas uptake. The results suggest that supramolecular design of ligands can be used to reveal this behaviour.

AB - Structural deformation in response to gas sorption is rarely observed for porous molecular solids, when compared to porous framework materials. Here, we describe the effect of chemical modification on the exterior of lantern-type metal-organic cages on the emergence and then disappearance of cooperative gas uptake. The results suggest that supramolecular design of ligands can be used to reveal this behaviour.

UR - http://www.scopus.com/inward/record.url?scp=85082542458&partnerID=8YFLogxK

U2 - 10.1039/d0cc00932f

DO - 10.1039/d0cc00932f

M3 - Article

C2 - 32123891

AN - SCOPUS:85082542458

SN - 1359-7345

VL - 56

SP - 3689

EP - 3692

JO - CHEMICAL COMMUNICATIONS

JF - CHEMICAL COMMUNICATIONS

IS - 25

ER -

Hysteresis in the gas sorption isotherms of metal-organic cages accompanied by subtle changes in molecular packing

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this