Illuminating the nature and behavior of the active center: The key for photocatalytic H2 production in Co@NH2-MIL-125(Ti)

Ana Iglesias-Juez; Sonia Castellanos; Manuel Monte; Giovanni Agostini; Dmitrii Osadchii; Maxim A. Nasalevich; Jara G. Santaclara; Alma I. Olivos Suarez; Sergey L. Veber; Matvey V. Fedin; Jorge Gascon

doi:10.1039/c8ta05735d

Illuminating the nature and behavior of the active center: The key for photocatalytic H₂ production in Co@NH₂-MIL-125(Ti)

Ana Iglesias-Juez, Sonia Castellanos, Manuel Monte, Giovanni Agostini, Dmitrii Osadchii, Maxim A. Nasalevich, Jara G. Santaclara, Alma I. Olivos Suarez, Sergey L. Veber, Matvey V. Fedin, Jorge Gascon

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

Advanced atomically resolved characterization methods unveil the mechanism of a promising photocatalytic Co@MOF(Ti) system for H₂ production. The combination of X-ray absorption spectroscopy (XAS) and electron paramagnetic resonance (EPR) experiments allows for the characterization of atomic and electronic rearrangements in the photoinduced species. This information provides the basis for the optimization of photocatalyst design.

Original language	English (US)
Pages (from-to)	17318-17322
Number of pages	5
Journal	JOURNAL OF MATERIALS CHEMISTRY A
Volume	6
Issue number	36
DOIs	https://doi.org/10.1039/c8ta05735d
State	Published - 2018

ASJC Scopus subject areas

General Chemistry
General Materials Science
Renewable Energy, Sustainability and the Environment

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1039/c8ta05735d

Cite this

Iglesias-Juez, A., Castellanos, S., Monte, M., Agostini, G., Osadchii, D., Nasalevich, M. A., Santaclara, J. G., Olivos Suarez, A. I., Veber, S. L., Fedin, M. V., & Gascon, J. (2018). Illuminating the nature and behavior of the active center: The key for photocatalytic H₂ production in Co@NH₂-MIL-125(Ti). JOURNAL OF MATERIALS CHEMISTRY A, 6(36), 17318-17322. https://doi.org/10.1039/c8ta05735d

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abstract = "Advanced atomically resolved characterization methods unveil the mechanism of a promising photocatalytic Co@MOF(Ti) system for H2 production. The combination of X-ray absorption spectroscopy (XAS) and electron paramagnetic resonance (EPR) experiments allows for the characterization of atomic and electronic rearrangements in the photoinduced species. This information provides the basis for the optimization of photocatalyst design.",

author = "Ana Iglesias-Juez and Sonia Castellanos and Manuel Monte and Giovanni Agostini and Dmitrii Osadchii and Nasalevich, {Maxim A.} and Santaclara, {Jara G.} and {Olivos Suarez}, {Alma I.} and Veber, {Sergey L.} and Fedin, {Matvey V.} and Jorge Gascon",

note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",

year = "2018",

doi = "10.1039/c8ta05735d",

language = "English (US)",

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Iglesias-Juez, A, Castellanos, S, Monte, M, Agostini, G, Osadchii, D, Nasalevich, MA, Santaclara, JG, Olivos Suarez, AI, Veber, SL, Fedin, MV & Gascon, J 2018, 'Illuminating the nature and behavior of the active center: The key for photocatalytic H₂ production in Co@NH₂-MIL-125(Ti)', JOURNAL OF MATERIALS CHEMISTRY A, vol. 6, no. 36, pp. 17318-17322. https://doi.org/10.1039/c8ta05735d

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AU - Castellanos, Sonia

AU - Monte, Manuel

AU - Agostini, Giovanni

AU - Osadchii, Dmitrii

AU - Nasalevich, Maxim A.

AU - Santaclara, Jara G.

AU - Olivos Suarez, Alma I.

AU - Veber, Sergey L.

AU - Fedin, Matvey V.

AU - Gascon, Jorge

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