TY - JOUR
T1 - Improved direct production of 2,3-dimethylbutenes and 3,3-dimethylbutene from 2-methylpropene on tungsten hydride based catalysts
AU - Garron, Anthony
AU - Stoffelbach, François
AU - Merle, Nicolas
AU - Szeto, Kaï Chung
AU - Thivolle-Cazat, Jean
AU - Basset, Jean-Marie
AU - Norsic, Sébastien
AU - Taoufik, Mostafa
N1 - KAUST Repository Item: Exported on 2020-10-01
PY - 2012
Y1 - 2012
N2 - 2-Methylpropene in the presence of W-H/Ni 1%-Al 2O 3-(500) is transformed in high selectivity into a mixture of 2,3-dimethylbutenes (2,3-DMBs = DMB-1 and DMB-2) and neohexene. 2,3-DMBs arise from the unfavoured 2-methylpropene self-metathesis reaction whereas the neohexene originates from a cascade reaction: 2-methylpropene dimerisation followed by cross metathesis. © 2012 The Royal Society of Chemistry.
AB - 2-Methylpropene in the presence of W-H/Ni 1%-Al 2O 3-(500) is transformed in high selectivity into a mixture of 2,3-dimethylbutenes (2,3-DMBs = DMB-1 and DMB-2) and neohexene. 2,3-DMBs arise from the unfavoured 2-methylpropene self-metathesis reaction whereas the neohexene originates from a cascade reaction: 2-methylpropene dimerisation followed by cross metathesis. © 2012 The Royal Society of Chemistry.
UR - http://hdl.handle.net/10754/562026
UR - http://xlink.rsc.org/?DOI=c2cy20539d
UR - http://www.scopus.com/inward/record.url?scp=84868709223&partnerID=8YFLogxK
U2 - 10.1039/c2cy20539d
DO - 10.1039/c2cy20539d
M3 - Article
SN - 2044-4753
VL - 2
SP - 2453
JO - Catalysis Science & Technology
JF - Catalysis Science & Technology
IS - 12
ER -