Incorporation of furan into low band-gap polymers for efficient solar cells

Claire H. Woo; Pierre Beaujuge; Thomas W. Holcombe; Olivia P. Lee; Jean Frechet

doi:10.1021/ja108115y

Incorporation of furan into low band-gap polymers for efficient solar cells

Claire H. Woo, Pierre Beaujuge, Thomas W. Holcombe, Olivia P. Lee, Jean Frechet

Research output: Contribution to journal › Article › peer-review

451 Scopus citations

Abstract

The design, synthesis, and characterization of the first examples of furan-containing low band-gap polymers, PDPP2FT and PDPP3F, with substantial power conversion efficiencies in organic solar cells are reported. Inserting furan moieties in the backbone of the conjugated polymers enables the use of relatively small solubilizing side chains because of the significant contribution of the furan rings to overall polymer solubility in common organic solvents. Bulk heterojunction solar cells fabricated from furan-containing polymers and PC₇₁BM as the acceptor showed power conversion efficiencies reaching 5.0%.

Original language	English (US)
Pages (from-to)	15547-15549
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	132
Issue number	44
DOIs	https://doi.org/10.1021/ja108115y
State	Published - Nov 10 2010

ASJC Scopus subject areas

General Chemistry
Biochemistry
Catalysis
Colloid and Surface Chemistry

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10.1021/ja108115y

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title = "Incorporation of furan into low band-gap polymers for efficient solar cells",

abstract = "The design, synthesis, and characterization of the first examples of furan-containing low band-gap polymers, PDPP2FT and PDPP3F, with substantial power conversion efficiencies in organic solar cells are reported. Inserting furan moieties in the backbone of the conjugated polymers enables the use of relatively small solubilizing side chains because of the significant contribution of the furan rings to overall polymer solubility in common organic solvents. Bulk heterojunction solar cells fabricated from furan-containing polymers and PC71BM as the acceptor showed power conversion efficiencies reaching 5.0%.",

author = "Woo, {Claire H.} and Pierre Beaujuge and Holcombe, {Thomas W.} and Lee, {Olivia P.} and Jean Frechet",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was supported by the Director, Office of Science, Office of Basic Energy Sciences, Materials Sciences and Engineering Division, of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231, and by the Center for Advanced Molecular Photovoltaics (Award No. KUS-C1-015-21), supported by King Abdullah University of Science and Technology (KAUST). C.H.W. and T.W.H. thank the National Science Foundation for graduate research fellowships. This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

year = "2010",

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doi = "10.1021/ja108115y",

language = "English (US)",

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AU - Woo, Claire H.

AU - Beaujuge, Pierre

AU - Holcombe, Thomas W.

AU - Lee, Olivia P.

AU - Frechet, Jean

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was supported by the Director, Office of Science, Office of Basic Energy Sciences, Materials Sciences and Engineering Division, of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231, and by the Center for Advanced Molecular Photovoltaics (Award No. KUS-C1-015-21), supported by King Abdullah University of Science and Technology (KAUST). C.H.W. and T.W.H. thank the National Science Foundation for graduate research fellowships. This publication acknowledges KAUST support, but has no KAUST affiliated authors.

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AB - The design, synthesis, and characterization of the first examples of furan-containing low band-gap polymers, PDPP2FT and PDPP3F, with substantial power conversion efficiencies in organic solar cells are reported. Inserting furan moieties in the backbone of the conjugated polymers enables the use of relatively small solubilizing side chains because of the significant contribution of the furan rings to overall polymer solubility in common organic solvents. Bulk heterojunction solar cells fabricated from furan-containing polymers and PC71BM as the acceptor showed power conversion efficiencies reaching 5.0%.

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Incorporation of furan into low band-gap polymers for efficient solar cells

Abstract

ASJC Scopus subject areas

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