Influence of steric crowding at the heteroatom on the metathesis of functionalized olefins: the polymerization of alkylthiocyclooctenes catalyzed by a metallacyclic aryloxo(chloro)neopentylidenetungsten complex

Jean Luc Couturier; Michel Leconte; Jean Marie Basset; Jean Ollivier

doi:10.1016/0022-328X(93)83035-T

Influence of steric crowding at the heteroatom on the metathesis of functionalized olefins: the polymerization of alkylthiocyclooctenes catalyzed by a metallacyclic aryloxo(chloro)neopentylidenetungsten complex

Jean Luc Couturier^*, Michel Leconte, Jean Marie Basset, Jean Ollivier

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The ring-opening metathesis polymerization of various alkylthiocyclooctenes was successfully carried out in the presence of a metallacyclic aryloxo (chloro)neopentylidenetungsten complex. The polymerization rates depend strongly on the steric crowding of the alkylthio substituent which confirms that coordination of the heteroatom to the metal is one of the important factors that govern the rate of the metathesis of this type of functionalized olefin.

Original language	English (US)
Pages (from-to)	C7-C9
Journal	Journal of Organometallic Chemistry
Volume	451
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(93)83035-T
State	Published - Jun 1 1993
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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Couturier, J. L., Leconte, M., Basset, J. M., & Ollivier, J. (1993). Influence of steric crowding at the heteroatom on the metathesis of functionalized olefins: the polymerization of alkylthiocyclooctenes catalyzed by a metallacyclic aryloxo(chloro)neopentylidenetungsten complex. Journal of Organometallic Chemistry, 451(1-2), C7-C9. https://doi.org/10.1016/0022-328X(93)83035-T

@article{00e407b2c2bc49ea901d664616502154,

title = "Influence of steric crowding at the heteroatom on the metathesis of functionalized olefins: the polymerization of alkylthiocyclooctenes catalyzed by a metallacyclic aryloxo(chloro)neopentylidenetungsten complex",

abstract = "The ring-opening metathesis polymerization of various alkylthiocyclooctenes was successfully carried out in the presence of a metallacyclic aryloxo (chloro)neopentylidenetungsten complex. The polymerization rates depend strongly on the steric crowding of the alkylthio substituent which confirms that coordination of the heteroatom to the metal is one of the important factors that govern the rate of the metathesis of this type of functionalized olefin.",

author = "Couturier, {Jean Luc} and Michel Leconte and Basset, {Jean Marie} and Jean Ollivier",

year = "1993",

month = jun,

day = "1",

doi = "10.1016/0022-328X(93)83035-T",

language = "English (US)",

volume = "451",

pages = "C7--C9",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "1-2",

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Couturier, JL, Leconte, M, Basset, JM & Ollivier, J 1993, 'Influence of steric crowding at the heteroatom on the metathesis of functionalized olefins: the polymerization of alkylthiocyclooctenes catalyzed by a metallacyclic aryloxo(chloro)neopentylidenetungsten complex', Journal of Organometallic Chemistry, vol. 451, no. 1-2, pp. C7-C9. https://doi.org/10.1016/0022-328X(93)83035-T

Influence of steric crowding at the heteroatom on the metathesis of functionalized olefins: the polymerization of alkylthiocyclooctenes catalyzed by a metallacyclic aryloxo(chloro)neopentylidenetungsten complex. / Couturier, Jean Luc; Leconte, Michel; Basset, Jean Marie et al.
In: Journal of Organometallic Chemistry, Vol. 451, No. 1-2, 01.06.1993, p. C7-C9.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Influence of steric crowding at the heteroatom on the metathesis of functionalized olefins

T2 - the polymerization of alkylthiocyclooctenes catalyzed by a metallacyclic aryloxo(chloro)neopentylidenetungsten complex

AU - Couturier, Jean Luc

AU - Leconte, Michel

AU - Basset, Jean Marie

AU - Ollivier, Jean

PY - 1993/6/1

Y1 - 1993/6/1

N2 - The ring-opening metathesis polymerization of various alkylthiocyclooctenes was successfully carried out in the presence of a metallacyclic aryloxo (chloro)neopentylidenetungsten complex. The polymerization rates depend strongly on the steric crowding of the alkylthio substituent which confirms that coordination of the heteroatom to the metal is one of the important factors that govern the rate of the metathesis of this type of functionalized olefin.

AB - The ring-opening metathesis polymerization of various alkylthiocyclooctenes was successfully carried out in the presence of a metallacyclic aryloxo (chloro)neopentylidenetungsten complex. The polymerization rates depend strongly on the steric crowding of the alkylthio substituent which confirms that coordination of the heteroatom to the metal is one of the important factors that govern the rate of the metathesis of this type of functionalized olefin.

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U2 - 10.1016/0022-328X(93)83035-T

DO - 10.1016/0022-328X(93)83035-T

M3 - Article

AN - SCOPUS:0002231582

SN - 0022-328X

VL - 451

SP - C7-C9

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Influence of steric crowding at the heteroatom on the metathesis of functionalized olefins: the polymerization of alkylthiocyclooctenes catalyzed by a metallacyclic aryloxo(chloro)neopentylidenetungsten complex

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